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Dissolved inorganic carbon (DIC), total alkalinity, pH on seawater scale, chlorofluorocarbon 12 (CFC-12), nutrients, water temperature, salinity, dissolved oxygen and other hydrographic and chemical data collected from discrete samples and profile observations during the R/V Johan Hjort cruise JH2019205 (EXPOCODE 58JH20190515) in the North Atlantic Ocean, Nordic Seas from 2019-05-15 to 2019-06-04 (NCEI Accession 0236506)

INVESTIGATORS:
Siv K. Lauvset ORCID logo - Bjerknes Centre for Climate Research
Meike Becker ORCID logo - GEOMAR Helmholtz Centre for Ocean Research Kiel, Kiel, Germany
Linda Fonnes Lunde - Institute of Marine Research - Norway (IMR)
Kristin Jackson-Misje -

PACKAGE DESCRIPTION: This dataset consists of dissolved inorganic carbon (DIC), total alkalinity, pH on seawater scale, chlorofluorocarbon 12 (CFC-12), nutrients, water temperature, salinity, dissolved oxygen and other hydrographic and chemical data collected from discrete samples and profile observations during the R/V Johan Hjort cruise JH2019205 (EXPOCODE 58JH20190515) in the North Atlantic Ocean, Nordic Seas from 2019-05-15 to 2019-06-04. The purpose was to monitoring of the IMR standard transects Svinøy, Gimsøy, Bjørnøya-Vest, and Fugløya-Bjørnøya. IMR takes biological (plankton), chemical (macronutrients, chlorophyll), and physical (CTD, ADCP) data at these sections several times every year. In addition, several Argo-floats were deployed. In order to get validation samples for the BGC-Argo floats staff from UiB and NORCE joined the cruise to collect and analyze carbonate chemistry (DIC, AT, pH), oxygen, and trace gas (CFC-12, SF6) data. This metadata describes these chemical data, as well as the macronutrients and salinity data.

CITE AS: Lauvset, Siv K.; Becker, Meike; Jackson-Misje, Kristin; Lunde, Linda Fonnes (2021). Dissolved inorganic carbon (DIC), total alkalinity, pH on seawater scale, chlorofluorocarbon 12 (CFC-12), nutrients, water temperature, salinity, dissolved oxygen and other hydrographic and chemical data collected from discrete samples and profile observations during the R/V Johan Hjort cruise JH2019205 (EXPOCODE 58JH20190515) in the North Atlantic Ocean, Nordic Seas from 2019-05-15 to 2019-06-04 (NCEI Accession 0236506). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://www.ncei.noaa.gov/archive/accession/0236506. Accessed [date].


IDENTIFICATION INFORMATION FOR THIS DATA PACKAGE:
NCEI ACCESSION: 0236506
EXPOCODE: 58JH20190515;
CRUISE ID: JH2019205;
SECTION/LEG: Bjørnoya Vest; Fugloya-Bjoernoya; Gimsoy; Svinoy;

TYPES OF STUDY:
Discrete measurement;

TEMPORAL COVERAGE:
START DATE: 2019-05-15
END DATE: 2019-06-04

SPATIAL COVERAGE:
NORTH: 74.5
WEST: -4.75
EAST: 20
SOUTH: 62.95

GEOGRAPHIC NAMES:
North Atlantic Ocean;Nordic Seas;

PLATFORMS:
R/V Johan Hjort (ID: 58JH);

RESEARCH PROJECT(S):
none;


VARIABLES / PARAMETERS:

Dissolved Inorganic Carbon
Abbreviation: TCARBN
Unit: micro-mol per kg
Observation type: profile
Measured or calculated: measured
Calculation method and parameters: NA
Sampling instrument: niskin
Analyzing instrument: VINDTA 3D
Detailed sampling and analyzing information: Onboard samples were drawn from niskin bottles following SOP as outlined in Dickson et al (2007) and analyzed immediately (no poisoning). Samples taken for analysis on land were drawn from niskin bottles following SOP as outlined in Dickson et al (2007), poisoned with HgCl2 and stored in a dark cool environment. Samples were analyzed within 6 weeks of end of cruise.
Replicate information: 1 full test where all niskins were filled at same depth; one sample analyzed twice in a row on 50% of stations
Standardization description: CRM
Standardization frequency: CRM analyzed before and after each full profile
CRM manufacturer: Andrew Dickson
Preservation method: HgCl2
Preservative volume: one drop in 500mL volume
Preservative correction: none
Uncertainty: 1.5 micro-mol per kg
Quality flag convention: WOCE flags: 2=acceptable; 3=questionable; 4=bad; 6=mean of replicates;9=missing
Method reference: Dickson 2007
Researcher name: Siv K. Lauvset
Researcher institution: NORCE Norwegian Research Centre
Total alkalinity
Abbreviation: ALKALI
Unit: micro-mol per kg
Observation type: profile
Measured or calculated: measured
Calculation method and parameters: NA
Sampling instrument: niskin
Analyzing instrument: VINDTA 3S
Type of titration: double endpoint
Cell type (open or closed): open
Curve fitting method: non-linear curve fitting using results from a modified GRAN plot
Detailed sampling and analyzing information: Onboard samples were drawn from niskin bottles following SOP as outlined in Dickson et al (2007) and analyzed immediately (no poisoning). Samples taken for analysis on land were drawn from niskin bottles following SOP as outlined in Dickson et al. (2007), poisoned with HgCl2 and stored in a dark cool environment. Samples were analyzed within 6 weeks of end of cruise.
Replicate information: none
Standardization description: CRM
Standardization frequency: CRM analyzed before and after each full profile
CRM manufacturer: Andrew Dickson
Preservation method: HgCl2
Preservative volume: one drop in 500mL volume
Preservative correction: none
TA blank correction: NA
Uncertainty: 2.5 micro-mol per kg
Quality flag convention: WOCE flags: 2=acceptable; 3=questionable; 4=bad; 6=mean of replicates;9=missing
Method reference: Dickson et al. 2007
Researcher name: Siv K. Lauvset
Researcher institution: NORCE Norwegian Research Centre
pH
Abbreviation: PH_TOT
pH scale: total
Observation type: profile
Measured or calculated: measured
Calculation method and parameters: NA
Sampling instrument: niskin
Analyzing instrument: Jasco spectrophotometer
Temperature of pH measurement: 25C on stations 488-535 and 575-592, ~20C on stations 536-569. All pH data were recalculated to 25C and are presented at that temperature in the data file
Detailed sampling and analyzing information: Samples drawn from niskins into 250mL glass bottles following Dickson et al (2007). For leg 1 we used a water jacketed 10cm cell for temperature control, and automated pumping. Analysis following Carter et al (2013). For leg 2 we were unable to use the water jacketed cell so instead used a normal 10cm cell. Temperature was measured and recorded before and after analysis. Analysis following Carter et al (2013). Data corrected to 25C after analysis (using the measured AT)
Replicate information: one duplicate run on each profile
Standardization description: TRIS and CRM
Standardization frequency: CRM run at least once for each full profile. Each CRM run 2-4 times for replication analysis. We brought 10 bottles of TRIS. These were analyzed at regular intervals throughout the cruise
pH standard values: TRIS: 8.0932; CRM: 7.883 (calculated from certified DIC and AT values using Merhbach K1/K2 constants refit by Dickson and Millero, Dickson for KSO4 constant, Lee et al for total boron, Dickson and Riley for KF constant)
Temperature of standardization: 25C
Temperature correction method: CO2SYS with measured AT
At what temperature was pH reported: 25C
Quality flag convention: WOCE flags: 2=acceptable; 3=questionable; 4=bad; 6=mean of replicates;9=missing
Method reference: Carter et al 2013
Researcher name: Siv K. Lauvset
Researcher institution: NORCE Norwegian Research Centre
dissolved oxygen in seawater
Abbreviation: OXYGEN
Unit: micro-mol per kg
Observation type: profile
Sampling instrument: niskin
Analyzing instrument: winkler
Detailed sampling and analyzing information: Samples were drawn from niskin bottles and analyzed immediately following SOP as outlined in Dickson et al (2007)
Replicate information: 1 station where all niskins were closed at the same depth; 2 stations where two niskins were closed at each depth
Uncertainty: 0.3 micro-mol per kg
Quality flag convention: WOCE flags: 2=acceptable; 3=questionable; 4=bad; 6=mean of replicates;9=missing
Method reference: https://www.go-ship.org/HydroMan.html
Researcher name: Kristin Jackson-Misje
Researcher institution: University of Bergen
salinity
Abbreviation: SALNTY
Unit: NA
Observation type: profile
Sampling instrument: niskin
Analyzing instrument: Guildline Portasal 8410A, serial no 68244
Detailed sampling and analyzing information: sampling and analysis following GO-SHIP protocols
Replicate information: none
Quality flag convention: WOCE flags: 2=acceptable; 3=questionable; 4=bad; 6=mean of replicates;9=missing
Method reference: https://www.go-ship.org/HydroMan.html
Researcher name: Kristin Jackson-Misje
Researcher institution: University of Bergen
inorganic nitrate
Abbreviation: NITRAT
Unit: micro-mol per kg
Observation type: profile
Sampling instrument: niskin
Analyzing instrument: Skalar autoanalyser
Detailed sampling and analyzing information: Samples were taken in plastic containers, poisoned with chloroform and kept refridgerated until analysis after the cruise. Spectrophotometric analysis of absorption at 540nm after reduction to nitrite using cadmium in the presence of copper-ions. Nitrate is the difference between this nitrite measurement and that without cadmium (see below)
Replicate information: none
Uncertainty: 0.5 micro-mol per liter
Quality flag convention: WOCE flags: 2=acceptable; 3=questionable; 4=bad; 6=mean of replicates;9=missing
Method reference: Bendschneider, K. and Robinson, R.I. (1952) A new Spectrophotometric method for the determination of nitrite in Seawater. J. Mar. Res. 2:87-96
Researcher name: Linda Fonnes Lunde
Researcher institution: Institute of Marine Research
inorganic nitrite
Abbreviation: NITRIT
Unit: micro-mol per kg
Observation type: profile
Sampling instrument: niskin
Analyzing instrument: Skalar autoanalyser
Detailed sampling and analyzing information: Samples were taken in plastic containers, poisoned with chloroform and kept refridgerated until analysis after the cruise. Spectrophotometric analysis of absorption at 540nm
Replicate information: none
Uncertainty: 0.06 micro-mol per liter
Quality flag convention: WOCE flags: 2=acceptable; 3=questionable; 4=bad; 6=mean of replicates;9=missing
Method reference: Bendschneider, K. and Robinson, R.I. (1952) A new Spectrophotometric method for the determination of nitrite in Seawater. J. Mar. Res. 2:87-96
Researcher name: Linda Fonnes Lunde
Researcher institution: Institute of Marine Research
inorganic phosphate
Abbreviation: PHSPHT
Unit: micro-mol per kg
Observation type: profile
Sampling instrument: niskin
Analyzing instrument: Skalar autoanalyser
Detailed sampling and analyzing information: Samples were taken in plastic containers, poisoned with chloroform and kept refridgerated until analysis after the cruise. Spectrophotometric analysis of absorption at 880nm
Replicate information: none
Uncertainty: 0.06 micro-mol per liter
Quality flag convention: WOCE flags: 2=acceptable; 3=questionable; 4=bad; 6=mean of replicates;9=missing
Method reference: Grasshoff, K. (1965) On the Automatic Determination of Phosphate, Silicate and Fluoride in Seawater. ICES Hydrographic Committee Report No. 129
Researcher name: Linda Fonnes Lunde
Researcher institution: Institute of Marine Research
silicate
Abbreviation: SILCAT
Unit: micro-mol per kg
Observation type: profile
Sampling instrument: niskin
Analyzing instrument: Skalar autoanalyser
Detailed sampling and analyzing information: Samples were taken in plastic containers, poisoned with chloroform and kept refridgerated until analysis after the cruise. Spectrophotometric analysis of absorption at 810nm
Replicate information: none
Uncertainty: 0.7 micro-mol per liter
Quality flag convention: WOCE flags: 2=acceptable; 3=questionable; 4=bad; 6=mean of replicates;9=missing
Method reference: Grasshoff, K. (1965) On the Automatic Determination of Phosphate, Silicate and Fluoride in Seawater. ICES Hydrographic Committee Report No. 129
Researcher name: Linda Fonnes Lunde
Researcher institution: Institute of Marine Research
CFC-12
Abbreviation: CFC12
Unit: pmol/kg
Observation type: profile
Sampling instrument: niskin
Analyzing instrument: purge and trap with gas chromatograph
Detailed sampling and analyzing information: Samples were drawn from niskin bottles and analyzed immediately
Uncertainty: 2% or 0.004 pmol kg-1
Quality flag convention: WOCE flags: 2=acceptable; 3=questionable; 4=bad; 6=mean of replicates;9=missing
Method reference: Bullister and Tanhua
Researcher name: Meike Becker
Researcher institution: University of Bergen
SF6
Abbreviation: SF6
Unit: fmol/kg
Observation type: profile
Sampling instrument: niskin
Analyzing instrument: purge and trap with gas chromatograph
Detailed sampling and analyzing information: Samples were drawn from niskin bottles and analyzed immediately
Uncertainty: 3% or 0.03 fmol kg-1
Quality flag convention: WOCE flags: 2=acceptable; 3=questionable; 4=bad; 6=mean of replicates;9=missing
Method reference: Bullister and Tanhua
Researcher name: Meike Becker
Researcher institution: University of Bergen
dissolved oxygen in seawater
Abbreviation: CTDOXY
Unit: micro-mol per kg
Observation type: profile
Sampling instrument: SeaBird SBE 43
Analyzing instrument: NA
Detailed sampling and analyzing information: NA
Replicate information: NA
Uncertainty: unknown, data have not been calibrated with bottle data nor quality controlled, however crossovers with GLODAPv2.2019 data indicate these data are biased low by ~6% (below 1900m)
Quality flag convention: NA
Method reference: NA
Researcher name: NA
Researcher institution: NA
salinity
Abbreviation: CTDSAL
Unit: NA
Observation type: profile
Sampling instrument: SeaBird CTD
Analyzing instrument: NA
Detailed sampling and analyzing information: NA
Replicate information: NA
Uncertainty: unknown, data have not been calibrated with bottle data
Quality flag convention: WOCE flags: 2=acceptable; 3=questionable; 4=bad; 6=mean of replicates;9=missing
Method reference: NA
Researcher name: NA
Researcher institution: NA

PUBLICATIONS DESCRIBING THIS DATASET:
none;
ADDITIONAL INFORMATION:
These data should be acknowledged with: "Siv K Lauvset, Meike Becker, Kristin Jackson-Misje, Linda Fonnes Lunde (2020) Chemistry data on 58JH20190515 https://doi.org/10.21335/NMDC-2017470118"
FUNDING:
Research Council of Norway
PROJECT TITLE: NorArgo2
PROJECT ID:

SUBMITTED BY: Siv K. Lauvset (sivk@norceresearch.no)

SUBMISSION DATE: 2021-06-17