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Total dissolved copper, estimates of free Cu2+, ligand concentrations, and conditional stability constants from R/V Knorr KN199-04, KN204-01, subtropical North Atlantic Ocean from 2010-2011 (U.S. GEOTRACES NAT project) (NCEI Accession 0278259)

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This dataset contains chemical and physical data collected on R/V Knorr during cruises KN199-04 and KN204-01 in the North Atlantic Ocean on 2013-10-22. These data include depth and trace metal concentration. The instruments used to collect these data include BASi Controlled Growth Mercury Electrode, GO-FLO Teflon Trace Metal Bottle, GeoFish Towed near-Surface Sampler, and Mass Spectrometer. These data were collected by James W. Moffett of University of Southern California as part of the "U.S. GEOTRACES North Atlantic Transect (U.S. GEOTRACES NAT)" project and "U.S. GEOTRACES (U.S. GEOTRACES)" program. The Biological and Chemical Oceanography Data Management Office (BCO-DMO) submitted these data to NCEI on 2021-05-12.

The following is the text of the dataset description provided by BCO-DMO:

Total dissolved copper and estimates of free Cu2+, ligand concentrations, and conditional stability constants

Dataset Description:
Total dissolved copper and estimates of free Cu2+ and ligand concentrations and conditional stability constants.

Expanded/revised data was served on 5 Nov. 2013.

Please note that data may not be final, pending intercalibration results and further analysis. If you are interested in following changes to US GEOTRACES data, there is an RSS feed available from the GEOTRACES-NAT project page.

Dataset Citation

Cite as: Moffett, James W. (2023). Total dissolved copper, estimates of free Cu2+, ligand concentrations, and conditional stability constants from R/V Knorr KN199-04, KN204-01, subtropical North Atlantic Ocean from 2010-2011 (U.S. GEOTRACES NAT project) (NCEI Accession 0278259). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://www.ncei.noaa.gov/archive/accession/0278259. Accessed [date].

Dataset Identifiers

ISO 19115-2 Metadata

gov.noaa.nodc:0278259

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Download Data	HTTPS (download) Navigate directly to the URL for data access and direct download. FTP (download) These data are available through the File Transfer Protocol (FTP). FTP is no longer supported by most internet browsers. You may copy and paste the FTP link to the data into an FTP client (e.g., FileZilla or WinSCP).
Distribution Formats	TSV
Ordering Instructions	Contact NCEI for other distribution options and instructions.
Distributor	NOAA National Centers for Environmental Information +1-301-713-3277 NCEI.Info@noaa.gov
Dataset Point of Contact	NOAA National Centers for Environmental Information ncei.info@noaa.gov

Time Period	2013-10-22 to 2013-10-22
Spatial Bounding Box Coordinates	West: -69.803 East: -9.652 South: 17.35 North: 39.701
Spatial Coverage Map

General Documentation

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Descriptive Information
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Associated Resources

Biological, chemical, physical, biogeochemical, ecological, environmental and other data collected from around the world during historical and contemporary periods of biological and chemical oceanographic exploration and research managed and submitted by the Biological and Chemical Oceanography Data Management Office (BCO-DMO)
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Moffett, J. W. (2013) Total dissolved copper, estimates of free Cu2+, ligand concentrations, and conditional stability constants from R/V Knorr KN199-04, KN204-01, subtropical North Atlantic Ocean from 2010-2011 (U.S. GEOTRACES NAT project). Biological and Chemical Oceanography Data Management Office (BCO-DMO). (Version 1) Version Date 2013-10-22. https://doi.org/10.26008/1912/bco-dmo.3845.1
- https://doi.org/10.26008/1912/bco-dmo.3845.1 (download)
  originator dataset

gov.noaa.nodc:BCO-DMO

Publication Dates	publication: 2023-05-15
Data Presentation Form	Digital table - digital representation of facts or figures systematically displayed, especially in columns
Dataset Progress Status	Complete - production of the data has been completed Historical archive - data has been stored in an offline storage facility
Data Update Frequency	As needed
Supplemental Information	Acquisition Description: Samples for total dissolved Cu were acidified in accordance with the standard GEOTRACES protocol using Optima Grade hydrochloric acid. Samples for speciation determination were processed on board, or were frozen in a -20 freezer for analysis ashore. Speciation measurements were performed on samples that were titrated with increasing amounts of Cu, and the change in Cu complexation was determined using competitive ligand exchange cathodic stripping voltammetry, as described in Moffett and Dupont (2007). The raw data were fit to a speciation model using non-linear regression as described in Moffett and Dupont (2007).
Purpose	This dataset is available to the public for a wide variety of uses including scientific research and analysis.
Use Limitations	accessLevel: Public Distribution liability: NOAA and NCEI make no warranty, expressed or implied, regarding these data, nor does the fact of distribution constitute such a warranty. NOAA and NCEI cannot assume liability for any damages caused by any errors or omissions in these data. If appropriate, NCEI can only certify that the data it distributes are an authentic copy of the records that were accepted for inclusion in the NCEI archives.

Dataset Citation	Cite as: Moffett, James W. (2023). Total dissolved copper, estimates of free Cu2+, ligand concentrations, and conditional stability constants from R/V Knorr KN199-04, KN204-01, subtropical North Atlantic Ocean from 2010-2011 (U.S. GEOTRACES NAT project) (NCEI Accession 0278259). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://www.ncei.noaa.gov/archive/accession/0278259. Accessed [date].
Cited Authors	Moffett, James W. University of Southern California
Principal Investigators	James W. Moffett University of Southern California (USC)
Contributors	University of Southern California (USC)
Resource Providers	Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Points of Contact	Biological and Chemical Oceanography Data Management Office (BCO-DMO)
Publishers	NOAA National Centers for Environmental Information
Acknowledgments	Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-0927387 Award URL: http://www.nsf.gov/awardsearch/showAward.do?AwardNumber=0927387

Theme keywords	NODC DATA TYPES THESAURUS DEPTH - OBSERVATION TRACE METALS NODC OBSERVATION TYPES THESAURUS chemical physical WMO_CategoryCode oceanography BCO-DMO Standard Parameters ISO_DateTime_UTC Niskin bottle number Trace metal conc standard deviation bottle cast cruise id date_utc depth event flag latitude longitude no standard parameter sample identification station time_of_day trace metal concentration Global Change Master Directory (GCMD) Science Keywords EARTH SCIENCE > OCEANS > OCEAN CHEMISTRY Originator Parameter Names BTL_ISO_DateTime_UTC Cu Cu2_minus_std_err Cu2_plus_std_err Cu_plus2 Cu_std_dev Li Li_std_dev bottle_GEOTRC cast_GEOTRC cruise_id date depth_GEOTRC_CTD event_GEOTRC flag froz_fresh lat log_K lon sample_GEOTRC sample_bottle_GEOTRC station_GEOTRC
Data Center keywords	NODC COLLECTING INSTITUTION NAMES THESAURUS University of Southern California NODC SUBMITTING INSTITUTION NAMES THESAURUS Biological and Chemical Oceanography Data Management Office Global Change Master Directory (GCMD) Data Center Keywords BCO-DMO > Biological and Chemical Oceanography Data Management Office
Platform keywords	NODC PLATFORM NAMES THESAURUS R/V Knorr BCO-DMO Platform Names R/V Knorr Global Change Master Directory (GCMD) Platform Keywords Ships ICES/SeaDataNet Ship Codes KNORR (call sign: KCEJ, ICES code: 316N, 1970)
Instrument keywords	NODC INSTRUMENT TYPES THESAURUS bottle mass spectrometer BCO-DMO Standard Instruments BASi Controlled Growth Mercury Electrode GO-FLO Teflon Trace Metal Bottle GeoFish Towed near-Surface Sampler Mass Spectrometer Global Change Master Directory (GCMD) Instrument Keywords MASS SPECTROMETERS > MASS SPECTROMETERS Originator Instrument Names BASi Controlled Growth Mercury Electrode GO-FLO Teflon Trace Metal GeoFish Mass Spectrometer
Place keywords	NODC SEA AREA NAMES THESAURUS North Atlantic Ocean Global Change Master Directory (GCMD) Location Keywords OCEAN > ATLANTIC OCEAN > NORTH ATLANTIC OCEAN Provider Place Names Subtropical northern Atlantic Ocean
Project keywords	NODC PROJECT NAMES THESAURUS GEOTRACES BCO-DMO Standard Programs U.S. GEOTRACES (U.S. GEOTRACES) BCO-DMO Standard Projects U.S. GEOTRACES North Atlantic Transect (U.S. GEOTRACES NAT) Global Change Master Directory (GCMD) Project Keywords IPY-GEOTRACES > International Polar Year GEOTRACES: An international study of the biogeochemical cycles of Trace Elements and Isotopes in the Arctic and Southern Oceans Provider Cruise IDs KN199-04 KN204-01 Provider Funding Award Information Funding provided by NSF Division of Ocean Sciences (NSF OCE) Award Number: OCE-0927387
Keywords	NCEI ACCESSION NUMBER 0278259

Use Constraints	Cite as: Moffett, James W. (2023). Total dissolved copper, estimates of free Cu2+, ligand concentrations, and conditional stability constants from R/V Knorr KN199-04, KN204-01, subtropical North Atlantic Ocean from 2010-2011 (U.S. GEOTRACES NAT project) (NCEI Accession 0278259). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://www.ncei.noaa.gov/archive/accession/0278259. Accessed [date].
Data License	This dataset is licensed under a Creative Commons Attribution 4.0 International (CC BY 4.0) License. SPDX License: Creative Commons Attribution 4.0 International (CC-BY-4.0)
Access Constraints	Use liability: NOAA and NCEI cannot provide any warranty as to the accuracy, reliability, or completeness of furnished data. Users assume responsibility to determine the usability of these data. The user is responsible for the results of any application of this data for other than its intended purpose.
Fees	In most cases, electronic downloads of the data are free. However, fees may apply for custom orders, data certifications, copies of analog materials, and data distribution on physical media.

Lineage information for: dataset
Processing Steps	2023-05-15T06:38:39Z - NCEI Accession 0278259 v1.1 was published.
Output Datasets	NCEI Accession 0278259 v1.1 NCEI Accession 0278259 v1.1 (download) published 2023-05-15T06:38:39Z

Acquisition Information (collection)
Instrument	bottle mass spectrometer
Platform	R/V Knorr

Last Modified: 2024-05-31T15:15:28Z
For questions about the information on this page, please email: ncei.info@noaa.gov

Total dissolved copper, estimates of free Cu2+, ligand concentrations, and conditional stability constants from R/V Knorr KN199-04, KN204-01, subtropical North Atlantic Ocean from 2010-2011 (U.S. GEOTRACES NAT project) (NCEI Accession 0278259)

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