Surface underway measurements of partial pressure of carbon dioxide (pCO2) in the Mediterranean Sea and North Atlantic Ocean during the M/N Colibri Ships of Opportunity (SOOP) lines in 2022 (NCEI Accession 0260682)
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title: Surface underway measurements of partial pressure of carbon dioxide (pCO2) in the Mediterranean Sea and North Atlantic Ocean during the M/N Colibri Ships of Opportunity (SOOP) lines in 2022 (NCEI Accession 0260682)
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abstract: This dataset includes surface underway, chemical, meteorological and physical data collected from MN Colibri Ships of Opportunity (SOOP) lines in the Mediterranean Sea and North Atlantic Ocean from 2022-04-05 to 2022-11-17. These data include barometric pressure, partial pressure of carbon dioxide - atmosphere, partial pressure of carbon dioxide - water, sea surface salinity and temperature. The instruments used to collect these data include Carbon dioxide (CO2) gas analyzer.
purpose: This dataset is available to the public for a wide variety of uses including scientific research and analysis.
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title: Weiss, R. F. (1974). Carbon dioxide in water and seawater: the solubility of a non-ideal gas. Mar. Chem. 2: 203-215. https://doi.org/10.1016/0304-4203(74)90015-2
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title: NOAA National Centers for Environmental Information (2022). Ocean Carbon and Acidification Data System (OCADS). NOAA National Centers for Environmental Information. https://www.ncei.noaa.gov/products/ocean-carbon-acidification-data-system
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electronicMailAddress: NCEI.Info@noaa.gov
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fees: In most cases, electronic downloads of the data are free. However, fees may apply for custom orders, data certifications, copies of analog materials, and data distribution on physical media.
orderingInstructions: Contact NCEI for other distribution options and instructions.
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description: NCEI Accession 0260682 was revised and v2.2 was published.
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description: Parameter or Variable: SST; Abbreviation: SST; Unit: DEG_C; Controlled vocabulary name: SEA SURFACE TEMPERATURE; Observation type: Temperature from the ship's thermosalinograph (°C); In-situ / Manipulation / Response variable: in-situ; Analyzing instrument: SeaBird model SBE-21; Detailed sampling and analyzing information: Seawater samples are taken daily at the thermosalinograph outlet. Samples are analysed at SHOM-France in an OSIL Portasal, and compared to IAPSO Sea Water Standards. The thermosalinograph is calibrated every 18 months, either at Seabird-USA or at SHOM-France. The seawater inlet of both CO2 analyser and TSG is located on the sea chest. The TSG is very close to the hull, the sea water flow rate is 30 l/min. We consider that the temperature inside the TSG is the SST. The warming between the TSG and the CO2 analyser is 0.2°C (Tequ – TTSG).; Uncertainty: resolution: 0.001°C ; Temperature accuracy: ± 0.01°C.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SSS; Abbreviation: SSS; Unit: Sea surface salinity; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ; Analyzing instrument: SeaBird model SBE-21; Detailed sampling and analyzing information: Seawater samples are taken daily at the thermosalinograph outlet. Samples are analysed at SHOM-France in an OSIL Portasal, and compared to IAPSO Sea Water Standards; Uncertainty: Salinity resolution: 0.002 ‰; The salinity accuracy is expected to be ± 0.02 ‰.
processStep: (LE_ProcessStep)
description: Parameter or Variable: ATM_PRE; Abbreviation: ATM_PRE; Unit: Atm; Controlled vocabulary name: BAROMETRIC PRESSURE; In-situ / Manipulation / Response variable: in-situ; Analyzing instrument: Druck barometer RPT350; Detailed sampling and analyzing information: The barometric pressure was measured in the bridge, ~20 m above the equilibrator. The Druck barometer is placed in a box, which also contains the GPS and the Iridium transmitter. It was calibrated in March 2015.; Uncertainty: Accuracy: ± 0.01 %.
processStep: (LE_ProcessStep)
description: Parameter or Variable: EQ-TMP; Abbreviation: EQ-TMP; Unit: DEG_C; In-situ / Manipulation / Response variable: in-situ; Analyzing instrument: Hart model 1521 (April 2007 - present) with a 5610 thermistor probe; Detailed sampling and analyzing information: This thermometer was calibrated at SHOM - France in May 2013.; Uncertainty: Resolution: 0.001°C; Accuracy: ± 0.025°C.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Mole fraction of CO2 (dry) in air or equilibrated air (ppm); Abbreviation: xCO2; Unit: PPM, Mole fraction of CO2 (dry) in air or equilibrated air; Controlled vocabulary name: Partial pressure (or fugacity) of carbon dioxide - water; Observation type: Measured; In-situ / Manipulation / Response variable: in-situ; Analyzing instrument: LI-COR model 6262 (February 2006 - present) ftp://ftp.licor.com/perm/env/LI-6262/Manual/LI-6262_Manual.pdf CO2 resolution: 0.01 µmol/mol CO2 accuracy: ± 1 ppm at 350 ppm Pressure resolution: 0.02 hPa Internal pressure transducer accuracy: ± 1.2 hPa (Manufacturer specifications: ±0.1% FS, where FS = 0-1150 hPa); Detailed sampling and analyzing information: The general principle of instrumental design can be found in Pierrot et al. (2009). The concentration of CO2 in the headspace gas was measured using the adsorption of infrared (IR) radiation by the CO2 molecule. The LI-COR analyzer passed IR radiation through two cells. The reference cell is constantly flushed with a reference gas CO2-free. The sample cell is flushed with the gas of interest (standard, outside atmosphere, or headspace gas from equilibration chamber). The infrared analyzer is calibrated regularly using three standard gases (~250-~500 ppm) from Air Liquide - France, which were calibrated at DT INSU against primary NOAA standards for the high standard and at LSCE for the other two (ICOS Atmospheric Thematic Center). The exact concentrations of the standards are: 0 ppm (nitrogen gas) 270.55 ± 0.016 ppm 362.63 ± 0.014 ppm 503.83 ± 0.044 ppm The analyzer was checked by the manufacturer in June 2018.; Uncertainty: CO2 resolution: 0.01 µmol/mol; CO2 accuracy: ± 1 ppm at 350 ppm.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Water content of Licor in mmol/mol; Abbreviation: H2Omm; Unit: MMOL/MOL; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Equilibrator Pressure; Abbreviation: Pequ; Unit: hPa; In-situ / Manipulation / Response variable: in-situ; Analyzing instrument: Setra model 239, differential pressure; Detailed sampling and analyzing information: The pressure in the equilibrator relative to the bow thruster compartment was measured with a Setra model 239 differential barometer. The LI-COR barometer measured the barometric pressure of the compartment. The absolute pressure of the equilibrator headspace reported in data files is the sum of the infrared analyzer pressure and the differential pressure from the pressure transducer attached to the equilibrator.; Uncertainty: Resolution: 0.01 hPa; Accuracy: ± 0.052 hPa.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Fugacity in CO2 in seawater (µatm); Abbreviation: fCO2sw; Unit: UATM; Controlled vocabulary name: partial pressure of carbon dioxide - water; In-situ / Manipulation / Response variable: in-situ .
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metadataMaintenance: (MD_MaintenanceInformation)
maintenanceAndUpdateFrequency: (MD_MaintenanceFrequencyCode) asNeeded
maintenanceNote: Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.
maintenanceNote: NCEI Accession 0260682 was revised and a new version of the archival package was published. Updates to existing archival packages may provide additional files or replace obsolete files. The latest version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession. Please see journal.txt in the /about directory for additional details on changes made.
contact: (CI_ResponsibleParty)
organisationName: NOAA National Centers for Environmental Information
role: (CI_RoleCode) custodian
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acquisitionInformation: (MI_AcquisitionInformation)
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: barometric pressure sensor
type: barometric pressure sensor
description: instrument used to measure the atmospheric pressure.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: carbon dioxide (CO2) gas analyzer
type: carbon dioxide (CO2) gas analyzer
description: measures gaseous carbon dioxide Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption. Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water. To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: salinometer
type: salinometer
description: generic salinometer use salinometer when the instrument type used is unclear but the data include salinity measurements
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: showerhead equilibrator
type: showerhead equilibrator
description: extracts dissolved CO2 from water A carbon dioxide equilibrator is usually in the shape of a vertical tube, with a showerhead on the top, some headspace, a lot of beads to increase the surface exchange area between water and air, a water seal device at the bottom to allow water to overflow, but prevents air exchange between inside and outside. Carbon dioxide (CO2) equilibrator works together with carbon dioxide (CO2) gas analyzer (insttypes_id 183) to measure carbon dioxide in the water. To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: temperature sensor
type: temperature sensor
description: A sensor used to measure temperature.
platform: (MI_Platform)
identifier: (MD_Identifier)
code: MN COLIBRI
description: Additional information from ICES for the vessel MN COLIBRI from FRANCE. Name : MN COLIBRI Flag : FRANCE - FR (ISO Country Code) Call Sign : FNHO Platform Class : Ship IMO : 9207390 Current Length : 115 Built : 2000 Notes : Cargo - RoRo Additional Information Sources: - http://www.itu.int/cgi-bin/htsh/mars/ship_search.sh#start - http://www.vesseltracker.com/en/Ships/Mn-Colibri-9207390.html - http://www.shipspotting.com/gallery/photo.php?lid=1295602 - http://e-ships.net/ships.htm General Comments: IMO 9207390 Found in Miramar ship index and vesseltracker Confirmed by NOAA on 2012-12-05. Submitted to ICES on 2011-07-07.
instrument: (missing)
