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Surface underway measurements of partial pressure of carbon dioxide (pCO2) in the Mediterranean Sea and North Atlantic Ocean during the M/N Colibri Ships of Opportunity (SOOP) lines in 2022 (NCEI Accession 0260682)

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This dataset includes surface underway, chemical, meteorological and physical data collected from MN Colibri Ships of Opportunity (SOOP) lines in the Mediterranean Sea and North Atlantic Ocean from 2022-04-05 to 2022-11-17. These data include barometric pressure, partial pressure of carbon dioxide - atmosphere, partial pressure of carbon dioxide - water, sea surface salinity and temperature. The instruments used to collect these data include Carbon dioxide (CO2) gas analyzer.

Dataset Citation

Cite as: Lefèvre, Nathalie; Diverrès, Denis (2022). Surface underway measurements of partial pressure of carbon dioxide (pCO2) in the Mediterranean Sea and North Atlantic Ocean during the M/N Colibri Ships of Opportunity (SOOP) lines in 2022 (NCEI Accession 0260682). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://doi.org/10.25921/dyb6-2d94. Accessed [date].

Dataset Identifiers

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gov.noaa.nodc:0260682

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Download Data	HTTPS (download) Navigate directly to the URL for data access and direct download. FTP (download) These data are available through the File Transfer Protocol (FTP). FTP is no longer supported by most internet browsers. You may copy and paste the FTP link to the data into an FTP client (e.g., FileZilla or WinSCP).
Distribution Formats	Originator data format
Ordering Instructions	Contact NCEI for other distribution options and instructions.
Distributor	NOAA National Centers for Environmental Information +1-301-713-3277 NCEI.Info@noaa.gov
Dataset Point of Contact	NOAA National Centers for Environmental Information ncei.info@noaa.gov

Time Period	2022-04-05 to 2022-11-17
Spatial Bounding Box Coordinates	West: -80.589 East: 8.8 South: 5.514 North: 54.4
Spatial Coverage Map

General Documentation

Project Metadata
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Associated Resources

Pierrot, D., Neill, C., Sullivan, K., Castle, R., Wanninkhof, R., Lüger, H., Johannessen, T., Olsen, A., Feely, R. A., & Cosca, C. E. (2009). Recommendations for autonomous underway pCO2 measuring systems and data-reduction routines. Deep Sea Research Part II: Topical Studies in Oceanography, 56(8-10), 512-522. https://doi.org/10.1016/j.dsr2.2008.12.005
- https://doi.org/10.1016/j.dsr2.2008.12.005
  related journal article
Weiss, R. F. (1974). Carbon dioxide in water and seawater: the solubility of a non-ideal gas. Mar. Chem. 2: 203-215. https://doi.org/10.1016/0304-4203(74)90015-2
- https://doi.org/10.1016/0304-4203(74)90015-2
  journal article
MN Colibri Lines
- https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/Colibri.html
  related resource
NOAA National Centers for Environmental Information (2022). Ocean Carbon and Acidification Data System (OCADS). NOAA National Centers for Environmental Information. https://www.ncei.noaa.gov/products/ocean-carbon-acidification-data-system
- https://www.ncei.noaa.gov/products/ocean-carbon-acidification-data-system
  OCADS website

Publication Dates	publication: 2022-09-29 revision: 2023-12-21
Data Presentation Form	Digital table - digital representation of facts or figures systematically displayed, especially in columns
Dataset Progress Status	Complete - production of the data has been completed Historical archive - data has been stored in an offline storage facility
Data Update Frequency	As needed
Purpose	This dataset is available to the public for a wide variety of uses including scientific research and analysis.
Use Limitations	accessLevel: Public Distribution liability: NOAA and NCEI make no warranty, expressed or implied, regarding these data, nor does the fact of distribution constitute such a warranty. NOAA and NCEI cannot assume liability for any damages caused by any errors or omissions in these data. If appropriate, NCEI can only certify that the data it distributes are an authentic copy of the records that were accepted for inclusion in the NCEI archives.

Dataset Citation	Cite as: Lefèvre, Nathalie; Diverrès, Denis (2022). Surface underway measurements of partial pressure of carbon dioxide (pCO2) in the Mediterranean Sea and North Atlantic Ocean during the M/N Colibri Ships of Opportunity (SOOP) lines in 2022 (NCEI Accession 0260682). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://doi.org/10.25921/dyb6-2d94. Accessed [date].
Cited Authors	Lefèvre, Nathalie Diverrès, Denis French National Research Institute for Sustainable Development (IRD)
Principal Investigators	Nathalie Lefèvre UPMC; Oceanographic & Climate Laboratory: experiments and digital approaches (LOCEAN) Denis Diverrès French National Research Institute for Sustainable Development (IRD)
Contributors	UPMC; Oceanographic & Climate Laboratory: experiments and digital approaches (LOCEAN)
Resource Providers	Nathalie Lefèvre Sorbonne University (SU) UPMC; Oceanographic & Climate Laboratory: experiments and digital approaches (LOCEAN)
Publishers	NOAA National Centers for Environmental Information

Theme keywords	NODC DATA TYPES THESAURUS BAROMETRIC PRESSURE Partial pressure (or fugacity) of carbon dioxide - atmosphere partial pressure of carbon dioxide - water SALINITY - SURFACE WATER WATER TEMPERATURE xCO2 seawater NODC OBSERVATION TYPES THESAURUS chemical meteorological physical surface underway WMO_CategoryCode oceanography Global Change Master Directory (GCMD) Science Keywords EARTH SCIENCE > ATMOSPHERE > ATMOSPHERIC CHEMISTRY > CARBON AND HYDROCARBON COMPOUNDS > ATMOSPHERIC CARBON DIOXIDE > PARTIAL PRESSURE OF CARBON DIOXIDE EARTH SCIENCE > ATMOSPHERE > ATMOSPHERIC PRESSURE EARTH SCIENCE > CLIMATE INDICATORS > ATMOSPHERIC/OCEAN INDICATORS > SURFACE SALINITY EARTH SCIENCE > OCEANS > OCEAN CHEMISTRY > CARBON DIOXIDE EARTH SCIENCE > OCEANS > OCEAN TEMPERATURE > WATER TEMPERATURE EARTH SCIENCE > OCEANS > SALINITY/DENSITY > SALINITY OCADS Study Type Surface underway Provider Keywords SOOP VOS Provider Variable Abbreviations ATM_PRE EQ-TMP H2Omm Pequ SSS SST fCO2sw xCO2
Data Center keywords	NODC COLLECTING INSTITUTION NAMES THESAURUS UPMC; Oceanographic & Climate Laboratory: experiments and digital approaches NODC SUBMITTING INSTITUTION NAMES THESAURUS UPMC; Oceanographic & Climate Laboratory: experiments and digital approaches
Platform keywords	NODC PLATFORM NAMES THESAURUS MN COLIBRI Global Change Master Directory (GCMD) Platform Keywords Ships ICES/SeaDataNet Ship Codes MN COLIBRI (call sign: FNHO, ICES code: 35MJ)
Instrument keywords	NODC INSTRUMENT TYPES THESAURUS barometric pressure sensor carbon dioxide (CO2) gas analyzer salinometer showerhead equilibrator temperature sensor Global Change Master Directory (GCMD) Instrument Keywords BAROMETERS > BAROMETERS CO2 ANALYZERS > CO2 ANALYZERS EQUILIBRATORS SALINOMETERS TEMPERATURE SENSORS > TEMPERATURE SENSORS
Place keywords	NODC SEA AREA NAMES THESAURUS Mediterranean Sea North Atlantic Ocean North Sea Global Change Master Directory (GCMD) Location Keywords OCEAN > ATLANTIC OCEAN > NORTH ATLANTIC OCEAN OCEAN > ATLANTIC OCEAN > NORTH ATLANTIC OCEAN > MEDITERRANEAN SEA OCEAN > ATLANTIC OCEAN > NORTH ATLANTIC OCEAN > NORTH SEA Provider Geographic Names Mediterranean Sea North Atlantic Ocean
Project keywords	NODC PROJECT NAMES THESAURUS Ship of Opportunity Programme (SOOP) Surface Ocean CO2 Atlas (SOCAT) Cruise ID AX20 EXPOCODE 35MJ20220405 35MJ20220720 35MJ20220805 35MJ20221017 Ocean Acidification Search Keywords Ocean Carbon and Acidification Data System (OCADS) Project Reference Section ID SOOP
Keywords	NCEI ACCESSION NUMBER 0260682

Use Constraints	Cite as: Lefèvre, Nathalie; Diverrès, Denis (2022). Surface underway measurements of partial pressure of carbon dioxide (pCO2) in the Mediterranean Sea and North Atlantic Ocean during the M/N Colibri Ships of Opportunity (SOOP) lines in 2022 (NCEI Accession 0260682). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://doi.org/10.25921/dyb6-2d94. Accessed [date].
Access Constraints	Use liability: NOAA and NCEI cannot provide any warranty as to the accuracy, reliability, or completeness of furnished data. Users assume responsibility to determine the usability of these data. The user is responsible for the results of any application of this data for other than its intended purpose.
Fees	In most cases, electronic downloads of the data are free. However, fees may apply for custom orders, data certifications, copies of analog materials, and data distribution on physical media.

Lineage information for: dataset
Processing Steps	2022-09-29T18:40:36Z - NCEI Accession 0260682 v1.1 was published. 2023-12-21T17:40:27Z - NCEI Accession 0260682 was revised and v2.2 was published. Rationale: Updates were received for this dataset. These updates were copied into the data/0-data/ directory of this accession. These updates may provide additional files or replace obsolete files. This version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession.
Output Datasets	NCEI Accession 0260682 v1.1 NCEI Accession 0260682 v1.1 (download) published 2022-09-29T18:40:36Z NCEI Accession 0260682 v2.2 NCEI Accession 0260682 v2.2 (download) published 2023-12-21T17:40:27Z

Lineage information for: dataset

Processing Steps

2022-09-29T18:40:36Z - NCEI Accession 0260682 v1.1 was published.
2023-12-21T17:40:27Z - NCEI Accession 0260682 was revised and v2.2 was published.
Rationale: Updates were received for this dataset. These updates were copied into the data/0-data/ directory of this accession. These updates may provide additional files or replace obsolete files. This version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession.

Output Datasets

NCEI Accession 0260682 v1.1
- NCEI Accession 0260682 v1.1 (download)
  published 2022-09-29T18:40:36Z

NCEI Accession 0260682 v2.2
- NCEI Accession 0260682 v2.2 (download)
  published 2023-12-21T17:40:27Z

Lineage information for: dataset
Processing Steps	Parameter or Variable: SST; Abbreviation: SST; Unit: DEG_C; Controlled vocabulary name: SEA SURFACE TEMPERATURE; Observation type: Temperature from the ship's thermosalinograph (°C); In-situ / Manipulation / Response variable: in-situ; Analyzing instrument: SeaBird model SBE-21; Detailed sampling and analyzing information: Seawater samples are taken daily at the thermosalinograph outlet. Samples are analysed at SHOM-France in an OSIL Portasal, and compared to IAPSO Sea Water Standards. The thermosalinograph is calibrated every 18 months, either at Seabird-USA or at SHOM-France. The seawater inlet of both CO2 analyser and TSG is located on the sea chest. The TSG is very close to the hull, the sea water flow rate is 30 l/min. We consider that the temperature inside the TSG is the SST. The warming between the TSG and the CO2 analyser is 0.2°C (Tequ – TTSG).; Uncertainty: resolution: 0.001°C ; Temperature accuracy: ± 0.01°C. Parameter or Variable: SSS; Abbreviation: SSS; Unit: Sea surface salinity; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ; Analyzing instrument: SeaBird model SBE-21; Detailed sampling and analyzing information: Seawater samples are taken daily at the thermosalinograph outlet. Samples are analysed at SHOM-France in an OSIL Portasal, and compared to IAPSO Sea Water Standards; Uncertainty: Salinity resolution: 0.002 ‰; The salinity accuracy is expected to be ± 0.02 ‰. Parameter or Variable: ATM_PRE; Abbreviation: ATM_PRE; Unit: Atm; Controlled vocabulary name: BAROMETRIC PRESSURE; In-situ / Manipulation / Response variable: in-situ; Analyzing instrument: Druck barometer RPT350; Detailed sampling and analyzing information: The barometric pressure was measured in the bridge, ~20 m above the equilibrator. The Druck barometer is placed in a box, which also contains the GPS and the Iridium transmitter. It was calibrated in March 2015.; Uncertainty: Accuracy: ± 0.01 %. Parameter or Variable: EQ-TMP; Abbreviation: EQ-TMP; Unit: DEG_C; In-situ / Manipulation / Response variable: in-situ; Analyzing instrument: Hart model 1521 (April 2007 - present) with a 5610 thermistor probe; Detailed sampling and analyzing information: This thermometer was calibrated at SHOM - France in May 2013.; Uncertainty: Resolution: 0.001°C; Accuracy: ± 0.025°C. Parameter or Variable: Mole fraction of CO2 (dry) in air or equilibrated air (ppm); Abbreviation: xCO2; Unit: PPM, Mole fraction of CO2 (dry) in air or equilibrated air; Controlled vocabulary name: Partial pressure (or fugacity) of carbon dioxide - water; Observation type: Measured; In-situ / Manipulation / Response variable: in-situ; Analyzing instrument: LI-COR model 6262 (February 2006 - present) ftp://ftp.licor.com/perm/env/LI-6262/Manual/LI-6262_Manual.pdf CO2 resolution: 0.01 µmol/mol CO2 accuracy: ± 1 ppm at 350 ppm Pressure resolution: 0.02 hPa Internal pressure transducer accuracy: ± 1.2 hPa (Manufacturer specifications: ±0.1% FS, where FS = 0-1150 hPa); Detailed sampling and analyzing information: The general principle of instrumental design can be found in Pierrot et al. (2009). The concentration of CO2 in the headspace gas was measured using the adsorption of infrared (IR) radiation by the CO2 molecule. The LI-COR analyzer passed IR radiation through two cells. The reference cell is constantly flushed with a reference gas CO2-free. The sample cell is flushed with the gas of interest (standard, outside atmosphere, or headspace gas from equilibration chamber). The infrared analyzer is calibrated regularly using three standard gases (~250-~500 ppm) from Air Liquide - France, which were calibrated at DT INSU against primary NOAA standards for the high standard and at LSCE for the other two (ICOS Atmospheric Thematic Center). The exact concentrations of the standards are: 0 ppm (nitrogen gas) 270.55 ± 0.016 ppm 362.63 ± 0.014 ppm 503.83 ± 0.044 ppm The analyzer was checked by the manufacturer in June 2018.; Uncertainty: CO2 resolution: 0.01 µmol/mol; CO2 accuracy: ± 1 ppm at 350 ppm. Parameter or Variable: Water content of Licor in mmol/mol; Abbreviation: H2Omm; Unit: MMOL/MOL; In-situ / Manipulation / Response variable: in-situ. Parameter or Variable: Equilibrator Pressure; Abbreviation: Pequ; Unit: hPa; In-situ / Manipulation / Response variable: in-situ; Analyzing instrument: Setra model 239, differential pressure; Detailed sampling and analyzing information: The pressure in the equilibrator relative to the bow thruster compartment was measured with a Setra model 239 differential barometer. The LI-COR barometer measured the barometric pressure of the compartment. The absolute pressure of the equilibrator headspace reported in data files is the sum of the infrared analyzer pressure and the differential pressure from the pressure transducer attached to the equilibrator.; Uncertainty: Resolution: 0.01 hPa; Accuracy: ± 0.052 hPa. Parameter or Variable: Fugacity in CO2 in seawater (µatm); Abbreviation: fCO2sw; Unit: UATM; Controlled vocabulary name: partial pressure of carbon dioxide - water; In-situ / Manipulation / Response variable: in-situ .

Lineage information for: dataset

Processing Steps

Parameter or Variable: SST; Abbreviation: SST; Unit: DEG_C; Controlled vocabulary name: SEA SURFACE TEMPERATURE; Observation type: Temperature from the ship's thermosalinograph (°C); In-situ / Manipulation / Response variable: in-situ; Analyzing instrument: SeaBird model SBE-21; Detailed sampling and analyzing information: Seawater samples are taken daily at the thermosalinograph outlet. Samples are analysed at SHOM-France in an OSIL Portasal, and compared to IAPSO Sea Water Standards. The thermosalinograph is calibrated every 18 months, either at Seabird-USA or at SHOM-France. The seawater inlet of both CO2 analyser and TSG is located on the sea chest. The TSG is very close to the hull, the sea water flow rate is 30 l/min. We consider that the temperature inside the TSG is the SST. The warming between the TSG and the CO2 analyser is 0.2°C (Tequ – TTSG).; Uncertainty: resolution: 0.001°C ; Temperature accuracy: ± 0.01°C.
Parameter or Variable: SSS; Abbreviation: SSS; Unit: Sea surface salinity; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ; Analyzing instrument: SeaBird model SBE-21; Detailed sampling and analyzing information: Seawater samples are taken daily at the thermosalinograph outlet. Samples are analysed at SHOM-France in an OSIL Portasal, and compared to IAPSO Sea Water Standards; Uncertainty: Salinity resolution: 0.002 ‰; The salinity accuracy is expected to be ± 0.02 ‰.
Parameter or Variable: ATM_PRE; Abbreviation: ATM_PRE; Unit: Atm; Controlled vocabulary name: BAROMETRIC PRESSURE; In-situ / Manipulation / Response variable: in-situ; Analyzing instrument: Druck barometer RPT350; Detailed sampling and analyzing information: The barometric pressure was measured in the bridge, ~20 m above the equilibrator. The Druck barometer is placed in a box, which also contains the GPS and the Iridium transmitter. It was calibrated in March 2015.; Uncertainty: Accuracy: ± 0.01 %.
Parameter or Variable: EQ-TMP; Abbreviation: EQ-TMP; Unit: DEG_C; In-situ / Manipulation / Response variable: in-situ; Analyzing instrument: Hart model 1521 (April 2007 - present) with a 5610 thermistor probe; Detailed sampling and analyzing information: This thermometer was calibrated at SHOM - France in May 2013.; Uncertainty: Resolution: 0.001°C; Accuracy: ± 0.025°C.
Parameter or Variable: Mole fraction of CO2 (dry) in air or equilibrated air (ppm); Abbreviation: xCO2; Unit: PPM, Mole fraction of CO2 (dry) in air or equilibrated air; Controlled vocabulary name: Partial pressure (or fugacity) of carbon dioxide - water; Observation type: Measured; In-situ / Manipulation / Response variable: in-situ; Analyzing instrument: LI-COR model 6262 (February 2006 - present) ftp://ftp.licor.com/perm/env/LI-6262/Manual/LI-6262_Manual.pdf CO2 resolution: 0.01 µmol/mol CO2 accuracy: ± 1 ppm at 350 ppm Pressure resolution: 0.02 hPa Internal pressure transducer accuracy: ± 1.2 hPa (Manufacturer specifications: ±0.1% FS, where FS = 0-1150 hPa); Detailed sampling and analyzing information: The general principle of instrumental design can be found in Pierrot et al. (2009). The concentration of CO2 in the headspace gas was measured using the adsorption of infrared (IR) radiation by the CO2 molecule. The LI-COR analyzer passed IR radiation through two cells. The reference cell is constantly flushed with a reference gas CO2-free. The sample cell is flushed with the gas of interest (standard, outside atmosphere, or headspace gas from equilibration chamber). The infrared analyzer is calibrated regularly using three standard gases (~250-~500 ppm) from Air Liquide - France, which were calibrated at DT INSU against primary NOAA standards for the high standard and at LSCE for the other two (ICOS Atmospheric Thematic Center). The exact concentrations of the standards are: 0 ppm (nitrogen gas) 270.55 ± 0.016 ppm 362.63 ± 0.014 ppm 503.83 ± 0.044 ppm The analyzer was checked by the manufacturer in June 2018.; Uncertainty: CO2 resolution: 0.01 µmol/mol; CO2 accuracy: ± 1 ppm at 350 ppm.
Parameter or Variable: Water content of Licor in mmol/mol; Abbreviation: H2Omm; Unit: MMOL/MOL; In-situ / Manipulation / Response variable: in-situ.
Parameter or Variable: Equilibrator Pressure; Abbreviation: Pequ; Unit: hPa; In-situ / Manipulation / Response variable: in-situ; Analyzing instrument: Setra model 239, differential pressure; Detailed sampling and analyzing information: The pressure in the equilibrator relative to the bow thruster compartment was measured with a Setra model 239 differential barometer. The LI-COR barometer measured the barometric pressure of the compartment. The absolute pressure of the equilibrator headspace reported in data files is the sum of the infrared analyzer pressure and the differential pressure from the pressure transducer attached to the equilibrator.; Uncertainty: Resolution: 0.01 hPa; Accuracy: ± 0.052 hPa.
Parameter or Variable: Fugacity in CO2 in seawater (µatm); Abbreviation: fCO2sw; Unit: UATM; Controlled vocabulary name: partial pressure of carbon dioxide - water; In-situ / Manipulation / Response variable: in-situ .

Acquisition Information (collection)
Instrument	barometric pressure sensor carbon dioxide (CO2) gas analyzer salinometer showerhead equilibrator temperature sensor
Platform	MN COLIBRI

Last Modified: 2024-08-22T12:22:43Z
For questions about the information on this page, please email: ncei.info@noaa.gov

Surface underway measurements of partial pressure of carbon dioxide (pCO2) in the Mediterranean Sea and North Atlantic Ocean during the M/N Colibri Ships of Opportunity (SOOP) lines in 2022 (NCEI Accession 0260682)

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