Dissolved inorganic carbon (DIC), total alkalinity, pH on the total scale, water temperature, salinity and other measurements collected from discrete samples and profile observations under the Atlantic Zone Monitoring Program in the Estuary and Gulf of St. Lawrence from 2012-04-20 to 2020-10-30 (NCEI Accession 0227132)
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title: Dissolved inorganic carbon (DIC), total alkalinity, pH on the total scale, water temperature, salinity and other measurements collected from discrete samples and profile observations under the Atlantic Zone Monitoring Program in the Estuary and Gulf of St. Lawrence from 2012-04-20 to 2020-10-30 (NCEI Accession 0227132)
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abstract: This dataset includes discrete sample and profile data collected under the Atlantic Zone Monitoring Program in the Estuary and Gulf of St. Lawrence from 2012-04-20 to 2020-10-30. These data include water temperature, salinity, dissolved oxygen, nutrients, dissolved inorganic carbon (DIC), total alkalinity, pH on the total scale, and ammonium. The Atlantic Zone Monitoring Program (AZMP) was implemented in 1998 with the aim of increasing Fisheries and Oceans Canada's (DFO) capacity to understand, describe and forecast the state of the marine ecosystem and to quantify the changes in the ocean physical, chemical and biological properties. Ocean acidification is an emerging priority for Fisheries and Oceans Canada under the Aquatic Climate Change Adaption Services Program and is developing the knowledge-base necessary to support the development of adaptation tools and strategies and investing in science to better understand the specific consequences of a changing climate. Specifically, the effects of ocean acidification on ecosystems in the Northwest Atlantic and large aquatic basin risk assessments consider ocean acidification at the basin and sub-basin scale are being investigated.
purpose: The Atlantic Zone Monitoring Program (AZMP) was implemented in 1998 with the aim of increasing Fisheries and Oceans Canada's (DFO) capacity to understand; describe; and forecast the state of the marine ecosystem and to quantify the changes in the ocean physical; chemical and biological properties(i). A critical element of the AZMP involves an observation program aimed at assessing the variability in nutrients; phytoplankton and zooplankton. The overall aim is to identify fundamental relationships among elements of the planktonic ecosystem and establish how they respond to changes in environmental drivers(i). The AZMP derives its information on the state of the marine ecosystem from data collected at a network of sampling locations (high frequency sampling stations; cross-shelf sections; and groundfish surveys) in each region (Quebec; Gulf; Maritimes; NL) sampled at a frequency of biweekly to once annually.
credit: Funding Information: Government of Canada: Fisheries and Oceans Canada (Aquatic Climate Change Adaptation Services Program (ACCASP), 881-15K-96036)
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description: Parameter or Variable: Dissolved Inorganic Carbon; Abbreviation: TICW_01; Unit: umol / kg; Observation type: profile; Measured or calculated: measured; Sampling instrument: CTD and rosette bottle sampler: CTD model; sensors and other details to be specified in comment section; Analyzing instrument: Vindta 3C (Marianda; Kiel; Germany) which includes a UIC CO2 coulometer detector CM5017O (emulator CM5011; UIC.; Joliet; USA); Detailed sampling and analyzing information: Seawater samples were collected from standard depths in 500 mL borosilicate glass reagent bottles. Three mL of water was removed to allow room for thermal expansion and the sample was preserved within 30 minutes of collection with 0.250 mL of a mercuric chloride saturated solution; then sealed with Apiezon M grease and the ground glass stoppers secured in place with rubber bands. The samples were stored at room temperature until on-shore laboratory analysis. The samples were analysed for DIC using a Vindta 3C fully automated system in conjunction with a coulometer (UIC Inc.) to quantify total CO2 purged from the acidified sample. Measurements of a Certified reference material seawater (CRMs; Scripps Oceanographic Institution) were used for calibrating DIC with each batch of 13 samples by duplicate CRM measurements; Replicate information: Monoplicate sample / monoplicate measurement; Standardization description: Referenced to duplicate measurement of CRM prior to each daily batch of DIC; Standardization frequency: Each batch of 13 samples; CRM manufacturer: Andrew Dickson's Lab at Scripps Institute of Oceanography (co2crms@ucsd.edu); Preservation method: Mercuric chloride saturated solution; Preservative volume: 0.250 ml per 500 ml sample bottle = 0.05%; Preservative correction: None; Uncertainty: 1 umol.kg; Quality flag convention: "" = No QC Performed; 1 = Sample drawn from bottle but analysis not recieved; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Mean of replicate measurements; 7 = Manual chromatographic peak measurement; 8 = Irregular digital chromatographic peak integration; 9 = Not sampled; Method reference: Dickson; A.G.; Sabine; C.L. and Christian; J.R. (Eds.) 2007. Guide to Best Practices for Ocean CO2 Measurements. PICES Special Publication 3; 191 pp.; https://cdiac.ess-dive.lbl.gov/ftp/oceans/Handbook_2007/Guide_all_in_one.pdf.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Total alkalinity; Abbreviation: ALKW_02; Unit: umol / kg; Observation type: profile; Measured or calculated: measured; Sampling instrument: CTD and rosette bottle sampler: CTD model; sensors and other details to be specified in comment section; Analyzing instrument: Vindta 3C (Marianda; Kiel; Germany); Type of titration: Potentiometric multi point titration; Cell type (open or closed): Close; Curve fitting method: Gran point; Detailed sampling and analyzing information: Seawater samples were collected from standard depths in 500 mL borosilicate glass reagent bottles. Three mL of water was removed to allow room for thermal expansion and the sample was preserved within 30 minutes of collection with 0.250 mL of a mercuric chloride saturated solution; then sealed with Apiezon M grease and the ground glass stoppers secured in place with rubber bands. The samples were stored at room temperature until on-shore laboratory analysis. TA in the sample was determined by Vindta 3C fully automated system using a cell potentiometric titration with a Metrohm Titrando dosing (Dosino 800) with pH combined Aquatrode plus Metrohm electrode (6.0253.100). The multi-point titration ; using 0.1 M HCl titrant containing 35 g of sodium chloride per litre of acid; was performed in a temperature controlled held at 25 °C with Gran determination. Measurements of a Certified reference material seawater (CRMs; Scripps Oceanographic Institution) were used for calibrating TA with each batch of 13 samples by duplicate CRM measurements.; Replicate information: Monoplicate sample / monoplicate measurement; Standardization description: Referenced to duplicate measurement of CRM prior to each daily batch of samples; Standardization frequency: Each batch of 13 samples; CRM manufacturer: Andrew Dickson's Lab at Scripps Institute of Oceanography; Preservation method: Mercuric chloride saturated solution; Preservative volume: 100 uL (0.02 % by volume); Preservative correction: 0.250 ml per 500 ml sample bottle = 0.05%; TA blank correction: Averages between 10-40 umol / kg; Uncertainty: Assessed by computing the average standard deviation of duplicate water samples; Quality flag convention: "" = No QC Performed; 1 = Sample drawn from bottle but analysis not recieved; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Mean of replicate measurements; 7 = Manual chromatographic peak measurement; 8 = Irregular digital chromatographic peak integration; 9 = Not sampled; Method reference: This is method described in SOP 3a of Dickson; A.G.; Sabine; C.L. and Christian; J.R. (Eds.) 2007. Guide to Best Practices for Ocean CO2 Measurements. PICES Special Publication 3; 191 pp.
processStep: (LE_ProcessStep)
description: Parameter or Variable: pH; Abbreviation: pH_invitro_total_p; pH scale: Total scale; Observation type: profile; Measured or calculated: measured; Sampling instrument: CTD and rosette bottle sampler: CTD model; sensors and other details to be specified in comment section; Analyzing instrument: Perkin Elmer Lambda 2 spectrophotometer with 10 cm pathlength cell; Temperature of pH measurement: 25 degrees C; Detailed sampling and analyzing information: Seawater samples were collected from standard depths in 500 mL borosilicate glass reagent bottles. Three mL of water was removed to allow room for thermal expansion and the sample was preserved within 30 minutes of collection with 0.250 mL of a mercuric chloride saturated solution; then sealed with Apiezon M grease and the ground glass stoppers secured in place with rubber bands. The samples were stored at room temperature until on-shore laboratory analysis.  Just prior to measurement; the bottles were equilibrated to 25 degrees C in a water bath then transferred using the drawing tube into 10 cm quartz cell in an Perkin Elmer Lambda 2 spectrophotometer. Following a blank measurement; 40 mL of a 2 milli-molar solution of purified m-cresol purple was added to the sample and the cell shaken to mix the dye solution. Absorbances were measured at 434; 578 and 730 nm and pH determined according to the method described in SOP 6b of Guide to Best Practices for Ocean CO2 measurements (Dickson et al.; 2007).; Replicate information: Monoplicate sample / duplicate measurement; Standardization description: Referenced to duplicate measurements of a CRM before each daily batch of samples; Standardization frequency: Each 13 samples; pH standard values: According to CRM batch. Calculated from DIC and TA using CO2.SYS; Temperature of standardization: 25 degrees C; At what temperature was pH reported: 25 degrees C; Uncertainty: Typically 0.003; Quality flag convention: "" = No QC Performed; 1 = Sample drawn from bottle but analysis not recieved; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Mean of replicate measurements; 7 = Manual chromatographic peak measurement; 8 = Irregular digital chromatographic peak integration; 9 = Not sampled; Method reference: SOP 6b; Dickson; AG; Sabine; CL and Cristian; JR (Eds.) 2007. Guide to best practices for ocean CO2 measurement..
processStep: (LE_ProcessStep)
description: Parameter or Variable: pressure; Abbreviation: CTDPRS; Unit: decibars; Observation type: profile; Sampling instrument: SeaBird Scientific pressure sensor; SBE Digiquartz 6000 m pressure sensor; integrated in the 9plus CTD housing; Detailed sampling and analyzing information: SeaBird Scientific 9plus CTD-Rosette system; Replicate information: Primary and secondary sensors installed; Uncertainty: standard deviation calculated from dual pressure sensors; Quality flag convention: 1 = CTD not calibrated; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Interpolated over a pressure interval > 2dbar; 7 = Despiked; 8 = Bottle pair did not trip correctly; 9 = Not sampled; Method reference: https://www.seabird.com/profiling/sbe-911plus-ctd/family?productCategoryId=54627473769; Researcher name: Charlie Bishop; Researcher institution: Northwest Atlantic Fisheries Centre.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CHL-SENSOR insitu; Abbreviation: Chl_a_CTD_Fluor; Unit: mg/m3; Observation type: profile; Sampling instrument: CTD; Detailed sampling and analyzing information: Name - CHL-SENSOR insitu; Description - ; Preservative - not applicable; Storage - not applicable; Quality flag convention: 1 = CTD not calibrated; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Interpolated over a pressure interval > 2dbar; 7 = Despiked; 8 = Not used; 9 = Not sampled; Method reference: Insitu fluorometer calbrated and part of the CTD package; Researcher name: Data management - Scientific Advice Information and Support Branch (gddaiss-dmsaisb.XLAU@dfo-mpo.gc.ca).
processStep: (LE_ProcessStep)
description: Parameter or Variable: Chlorophyll A; Abbreviation: Chl_a_H-H_fresh; Unit: mg/m3; Observation type: profile; Sampling instrument: CTD; Analyzing instrument: AZMP sampling protocol; Detailed sampling and analyzing information: Name - Chlorophyll A; Description - ; Preservative - none; Storage - not applicable; Replicate information: Average of replicates; Quality flag convention: 1 = CTD not calibrated; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Interpolated over a pressure interval > 2dbar; 7 = Despiked; 8 = Not used; 9 = Not sampled; Method reference: Holm-Hansen; O; CJ Lorenzen; RW Holmes; JD Strickland (1965) Fluorometric determination of chlorophyll. J Cons Cons Int Explor Mer; 30†: 3-15.; Researcher name: Data management - Scientific Advice Information and Support Branch (gddaiss-dmsaisb.XLAU@dfo-mpo.gc.ca).
processStep: (LE_ProcessStep)
description: Parameter or Variable: Chlorophyll A; Abbreviation: Chl_a_Holm-Hansen_sF; Unit: mg/m3; Observation type: profile; Sampling instrument: CTD; Analyzing instrument: AZMP sampling protocol; Detailed sampling and analyzing information: Name - Chlorophyll A; Description - ; Preservative - frozen (-196); Storage - frozen (-80); Replicate information: Average of replicates; Quality flag convention: 1 = CTD not calibrated; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Interpolated over a pressure interval > 2dbar; 7 = Despiked; 8 = Not used; 9 = Not sampled; Method reference: Holm-Hansen; O; CJ Lorenzen; RW Holmes; JD Strickland (1965) Fluorometric determination of chlorophyll. J Cons Cons Int Explor Mer; 30†: 3-15.; Researcher name: Data management - Scientific Advice Information and Support Branch (gddaiss-dmsaisb.XLAU@dfo-mpo.gc.ca).
processStep: (LE_ProcessStep)
description: Parameter or Variable: Ammonia; Abbreviation: NH3_3; Unit: mmol/m3; Observation type: profile; Sampling instrument: CTD and rosette bottle sampler: CTD model; sensors and other details to be specified in comment section; Analyzing instrument: Unfiltered; Detailed sampling and analyzing information: Name - Ammonia; Description - ; Preservative - frozen; Storage - frozen; Replicate information: Average of replicates; Quality flag convention: 1 = CTD not calibrated; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Interpolated over a pressure interval > 2dbar; 7 = Despiked; 8 = Not used; 9 = Not sampled; Method reference: Holm-Hansen; O; CJ Lorenzen; RW Holmes; JD Strickland (1965) Fluorometric determination of chlorophyll. J Cons Cons Int Explor Mer; 30†: 3-15.; Researcher name: Data management - Scientific Advice Information and Support Branch (gddaiss-dmsaisb.XLAU@dfo-mpo.gc.ca).
processStep: (LE_ProcessStep)
description: Parameter or Variable: Nitrite; Abbreviation: NO2_Tech_SF; Unit: mmol/m3; Observation type: profile; Sampling instrument: CTD and rosette bottle sampler: CTD model; sensors and other details to be specified in comment section; Analyzing instrument: AZMP sampling protocol; Detailed sampling and analyzing information: Name - Nitrite; Description - ; Preservative - frozen (-196); Storage - frozen (-80); Replicate information: Average of replicates; Quality flag convention: "" = No QC Performed; 1 = Sample drawn from bottle but analysis not recieved; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Mean of replicate measurements; 7 = Manual chromatographic peak measurement; 8 = Irregular digital chromatographic peak integration; 9 = Not sampled; Method reference: American Public Health Association (1971) Standard Methods for the examination of water and wastewater. 13th edition; pp. 240-243; Washington D.C.; Researcher name: Data management - Scientific Advice Information and Support Branch (gddaiss-dmsaisb.XLAU@dfo-mpo.gc.ca).
processStep: (LE_ProcessStep)
description: Parameter or Variable: Nitrate; Abbreviation: NO2NO3_Tech_SF; Unit: mmol/m3; Observation type: profile; Sampling instrument: CTD and rosette bottle sampler: CTD model; sensors and other details to be specified in comment section; Analyzing instrument: AZMP sampling protocol; Detailed sampling and analyzing information: Name - Nitrite; Description - ; Preservative - frozen (-196); Storage - frozen (-80); Replicate information: Average of replicates; Quality flag convention: "" = No QC Performed; 1 = Sample drawn from bottle but analysis not recieved; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Mean of replicate measurements; 7 = Manual chromatographic peak measurement; 8 = Irregular digital chromatographic peak integration; 9 = Not sampled; Method reference: Armstrong; FAJ; CR Stearns; JDH Strickland (1967) The measurement of upwelling and subsequent biological processes by means of the Technicon Autoanalyzer and associated equipment. Deep-Sea Res 14(3) 381-389; Researcher name: Data management - Scientific Advice Information and Support Branch (gddaiss-dmsaisb.XLAU@dfo-mpo.gc.ca).
processStep: (LE_ProcessStep)
description: Parameter or Variable: O2; Abbreviation: O2_CTD_mLL; Unit: ml/l; Observation type: profile; Sampling instrument: CTD and rosette bottle sampler: CTD model; sensors and other details to be specified in comment section; Detailed sampling and analyzing information: Name - O2; Description - ; Preservative - not applicable; Storage - not applicable; Replicate information: Average of replicates; Quality flag convention: "" = No QC Performed; 1 = Sample drawn from bottle but analysis not recieved; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Mean of replicate measurements; 7 = Manual chromatographic peak measurement; 8 = Irregular digital chromatographic peak integration; 9 = Not sampled; Method reference: Calibrated sensor as part of the CTD package; Researcher name: Data management - Scientific Advice Information and Support Branch (gddaiss-dmsaisb.XLAU@dfo-mpo.gc.ca).
processStep: (LE_ProcessStep)
description: Parameter or Variable: O2; Abbreviation: O2_Winkler_Auto; Unit: ml/l; Observation type: profile; Sampling instrument: CTD and rosette bottle sampler: CTD model; sensors and other details to be specified in comment section; Detailed sampling and analyzing information: Name - O2; Description - ; Preservative - not applicable; Storage - not applicable; Replicate information: Average of replicates; Quality flag convention: "" = No QC Performed; 1 = Sample drawn from bottle but analysis not recieved; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Mean of replicate measurements; 7 = Manual chromatographic peak measurement; 8 = Irregular digital chromatographic peak integration; 9 = Not sampled; Method reference: Levy; E.M; C.C. Cunningham; C.D. Conrad and J.D. Moffat. 1977. A titration apparatus for the determination of dissolved Oxygen in seawater. J.Fish. Res. Board. Can. 34:2218-2220.; Researcher name: Data management - Scientific Advice Information and Support Branch (gddaiss-dmsaisb.XLAU@dfo-mpo.gc.ca).
processStep: (LE_ProcessStep)
description: Parameter or Variable: pH; Abbreviation: pH_CTD_cal-total; Observation type: profile; Sampling instrument: CTD; Detailed sampling and analyzing information: Name - pH; Description - ; Preservative - not applicable; Storage - not applicable; Quality flag convention: "" = No QC Performed; 1 = Sample drawn from bottle but analysis not recieved; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Mean of replicate measurements; 7 = Manual chromatographic peak measurement; 8 = Irregular digital chromatographic peak integration; 9 = Not sampled; Method reference: pH sensor; part of the CTD package; calibrated with lab measures; Researcher name: Data management - Scientific Advice Information and Support Branch (gddaiss-dmsaisb.XLAU@dfo-mpo.gc.ca).
processStep: (LE_ProcessStep)
description: Parameter or Variable: pH; Abbreviation: pH_insitu_total_p; Observation type: profile; Sampling instrument: CTD and rosette bottle sampler: CTD model; sensors and other details to be specified in comment section; Analyzing instrument: See Analysis Description; Detailed sampling and analyzing information: Name - pH; Description - ; Preservative - mercury chloride; Storage - room temp or refrigerated; Replicate information: Average of replicates; Quality flag convention: "" = No QC Performed; 1 = Sample drawn from bottle but analysis not recieved; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Mean of replicate measurements; 7 = Manual chromatographic peak measurement; 8 = Irregular digital chromatographic peak integration; 9 = Not sampled; Method reference: Dickson; AG; CL Sabine; JR Christian (eds) 2007. Guide to best practices for ocean CO2 measurements. PICES Special Publications 3; 191 pp./Lewis; E; and DWR Wallace (1998) CO2SYS-Program developed for CO2 system; Researcher name: Data management - Scientific Advice Information and Support Branch (gddaiss-dmsaisb.XLAU@dfo-mpo.gc.ca).
processStep: (LE_ProcessStep)
description: Parameter or Variable: pH; Abbreviation: pH_insitu_total_p; Observation type: profile; Sampling instrument: CTD and rosette bottle sampler: CTD model; sensors and other details to be specified in comment section; Analyzing instrument: See Analysis Description; Detailed sampling and analyzing information: Name - pH; Description - ; Preservative - mercury chloride; Storage - room temp or refrigerated; Replicate information: Average of replicates; Quality flag convention: "" = No QC Performed; 1 = Sample drawn from bottle but analysis not recieved; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Mean of replicate measurements; 7 = Manual chromatographic peak measurement; 8 = Irregular digital chromatographic peak integration; 9 = Not sampled; Method reference: Dickson; AG; CL Sabine; JR Christian (eds) 2007. Guide to best practices for ocean CO2 measurements. PICES Special Publications 3; 191 pp./Lewis; E; and DWR Wallace (1998) CO2SYS-Program developed for CO2 system; Researcher name: Data management - Scientific Advice Information and Support Branch (gddaiss-dmsaisb.XLAU@dfo-mpo.gc.ca).
processStep: (LE_ProcessStep)
description: Parameter or Variable: pH_invitro_temp; Abbreviation: pH_invitro_temp; Unit: degreesC; Observation type: profile; Sampling instrument: CTD and rosette bottle sampler: CTD model; sensors and other details to be specified in comment section; Detailed sampling and analyzing information: Name - pH_invitro_temp; Description - ; Preservative - not applicable; Storage - not applicable; Quality flag convention: "" = No QC Performed; 1 = Sample drawn from bottle but analysis not recieved; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Mean of replicate measurements; 7 = Manual chromatographic peak measurement; 8 = Irregular digital chromatographic peak integration; 9 = Not sampled; Method reference:; Researcher name: Data management - Scientific Advice Information and Support Branch (gddaiss-dmsaisb.XLAU@dfo-mpo.gc.ca).
processStep: (LE_ProcessStep)
description: Parameter or Variable: Phaeophytin; Abbreviation: Phaeo_H-H_fresh; Unit: mg/m3; Observation type: profile; Sampling instrument: CTD and rosette bottle sampler: CTD model; sensors and other details to be specified in comment section; Analyzing instrument: AZMP sampling protocol; Detailed sampling and analyzing information: Name - Phaeophytin; Description - ; Preservative - none; Storage - not applicable; Replicate information: Average of replicates; Quality flag convention: "" = No QC Performed; 1 = Sample drawn from bottle but analysis not recieved; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Mean of replicate measurements; 7 = Manual chromatographic peak measurement; 8 = Irregular digital chromatographic peak integration; 9 = Not sampled; Method reference: Holm-Hansen; O; CJ Lorenzen; RW Holmes; JD Strickland (1965) Fluorometric determination of chlorophyll. J Cons Cons Int Explor Mer; 30†: 3-15.; Researcher name: Data management - Scientific Advice Information and Support Branch (gddaiss-dmsaisb.XLAU@dfo-mpo.gc.ca).
processStep: (LE_ProcessStep)
description: Parameter or Variable: Phaeophytin; Abbreviation: Phaeo_Holm-Hansen; Unit: mg/m3; Observation type: profile; Sampling instrument: CTD and rosette bottle sampler: CTD model; sensors and other details to be specified in comment section; Analyzing instrument: AZMP sampling protocol; Detailed sampling and analyzing information: Name - Phaeophytin; Description - ; Preservative - frozen (-196); Storage - frozen (-80); Replicate information: Average of replicates; Quality flag convention: "" = No QC Performed; 1 = Sample drawn from bottle but analysis not recieved; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Mean of replicate measurements; 7 = Manual chromatographic peak measurement; 8 = Irregular digital chromatographic peak integration; 9 = Not sampled; Method reference: Holm-Hansen; O; CJ Lorenzen; RW Holmes; JD Strickland (1965) Fluorometric determination of chlorophyll. J Cons Cons Int Explor Mer; 30†: 3-15.; Researcher name: Data management - Scientific Advice Information and Support Branch (gddaiss-dmsaisb.XLAU@dfo-mpo.gc.ca).
processStep: (LE_ProcessStep)
description: Parameter or Variable: Phosphate; Abbreviation: PO4_Tech_SF; Unit: mmol/m3; Observation type: profile; Sampling instrument: CTD and rosette bottle sampler: CTD model; sensors and other details to be specified in comment section; Analyzing instrument: AZMP sampling protocol; Detailed sampling and analyzing information: Name - Phosphate; Description - ; Preservative - frozen (-196); Storage - frozen (-80); Replicate information: Average of replicates; Quality flag convention: "" = No QC Performed; 1 = Sample drawn from bottle but analysis not recieved; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Mean of replicate measurements; 7 = Manual chromatographic peak measurement; 8 = Irregular digital chromatographic peak integration; 9 = Not sampled; Method reference: Murphy; J; JP Riley (1962) A modified single solution method for the determination of phosphate in natural waters. Anal Chim. Acta 27†: 30.; Researcher name: Data management - Scientific Advice Information and Support Branch (gddaiss-dmsaisb.XLAU@dfo-mpo.gc.ca).
processStep: (LE_ProcessStep)
description: Parameter or Variable: Salinity; Abbreviation: Salinity_CTD; Observation type: profile; Sampling instrument: CTD and rosette bottle sampler: CTD model; sensors and other details to be specified in comment section; Analyzing instrument: CTD; Detailed sampling and analyzing information: Name - Salinity; Description - ; Preservative - not applicable; Storage - not applicable; Quality flag convention: "" = No QC Performed; 1 = Sample drawn from bottle but analysis not recieved; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Mean of replicate measurements; 7 = Manual chromatographic peak measurement; 8 = Irregular digital chromatographic peak integration; 9 = Not sampled; Researcher name: Data management - Scientific Advice Information and Support Branch (gddaiss-dmsaisb.XLAU@dfo-mpo.gc.ca).
processStep: (LE_ProcessStep)
description: Parameter or Variable: Salinity; Abbreviation: Salinity_Sal_PSS_Cal; Observation type: profile; Sampling instrument: CTD and rosette bottle sampler: CTD model; sensors and other details to be specified in comment section; Detailed sampling and analyzing information: Name - Salinity; Description - ; Preservative - not applicable; Storage - not applicable; Quality flag convention: "" = No QC Performed; 1 = Sample drawn from bottle but analysis not recieved; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Mean of replicate measurements; 7 = Manual chromatographic peak measurement; 8 = Irregular digital chromatographic peak integration; 9 = Not sampled; Method reference: Autosal salinometer; calibrated against standard seawater.; Researcher name: Data management - Scientific Advice Information and Support Branch (gddaiss-dmsaisb.XLAU@dfo-mpo.gc.ca).
processStep: (LE_ProcessStep)
description: Parameter or Variable: Secchi Depth; Abbreviation: Secchi_Depth_bw; Unit: m; Observation type: profile; Sampling instrument: secchi disk with black and white quarters; used to gauge water clarity by measuring the depth at which it is no longer visible from the surface; Detailed sampling and analyzing information: Name - secchi_depth; Description - ; Preservative - not applicable; Storage - not applicable; Quality flag convention: "" = No QC Performed; 1 = Sample drawn from bottle but analysis not recieved; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Mean of replicate measurements; 7 = Manual chromatographic peak measurement; 8 = Irregular digital chromatographic peak integration; 9 = Not sampled; Researcher name: Data management - Scientific Advice Information and Support Branch (gddaiss-dmsaisb.XLAU@dfo-mpo.gc.ca).
processStep: (LE_ProcessStep)
description: Parameter or Variable: Silicate; Abbreviation: SiO4_Tech_SF; Unit: mmol/m3; Observation type: profile; Sampling instrument: CTD and rosette bottle sampler: CTD model; sensors and other details to be specified in comment section; Analyzing instrument: AZMP sampling protocol; Detailed sampling and analyzing information: Name - Silicate; Description - ; Preservative - frozen (-196); Storage - frozen (-80); Replicate information: Average of replicates; Quality flag convention: "" = No QC Performed; 1 = Sample drawn from bottle but analysis not recieved; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Mean of replicate measurements; 7 = Manual chromatographic peak measurement; 8 = Irregular digital chromatographic peak integration; 9 = Not sampled; Method reference: Strickland; JDH; TR Parsons (1972) A Practical Handbook of Seawater Analysis; second edition. Fish Res Board Can; Bulletin 167; 310 pp; Researcher name: Data management - Scientific Advice Information and Support Branch (gddaiss-dmsaisb.XLAU@dfo-mpo.gc.ca).
processStep: (LE_ProcessStep)
description: Parameter or Variable: Temperature; Abbreviation: Temp_CTD_1990; Unit: Deg.C; Observation type: profile; Sampling instrument: CTD; Analyzing instrument: CTD; Detailed sampling and analyzing information: Name - Temperature; Description - ; Preservative - not applicable; Storage - not applicable; Quality flag convention: 1 = CTD not calibrated; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Interpolated over a pressure interval > 2dbar; 7 = Despiked; 8 = Not used; 9 = Not sampled; Method reference: Temperature measured at depth using calibrated sensor as part of CTD package; Researcher name: Data management - Scientific Advice Information and Support Branch (gddaiss-dmsaisb.XLAU@dfo-mpo.gc.ca) .
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metadataMaintenance: (MD_MaintenanceInformation)
maintenanceAndUpdateFrequency: (MD_MaintenanceFrequencyCode) asNeeded
maintenanceNote: Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.
maintenanceNote: NCEI Accession 0227132 was revised and a new version of the archival package was published. Updates to existing archival packages may provide additional files or replace obsolete files. The latest version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession. Please see journal.txt in the /about directory for additional details on changes made.
contact: (CI_ResponsibleParty)
organisationName: NOAA National Centers for Environmental Information
role: (CI_RoleCode) custodian
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acquisitionInformation: (MI_AcquisitionInformation)
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: carbon dioxide (CO2) gas analyzer
type: carbon dioxide (CO2) gas analyzer
description: measures gaseous carbon dioxide Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption. Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water. To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: CTD
type: CTD
description: Conductivity-Temperature-Depth probe
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: Niskin bottle
type: Niskin bottle
description: Device for obtaining samples of seawater at a specific depth Why special entry for Niskin bottle but no entry for Nansen bottle?
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: nutrient autoanalyzer
type: nutrient autoanalyzer
description: Laboratory Instrument Nutrient Autoanalyzer is a generic term describing an automated flow-thru system used to conduct analyses of several different nutrients (nitrate, ammonium, orthophosphate, and silicate) simultaneously from a seawater sample. For example: SEAL AutoAnalyzer 3 HR Continuous Segmented Flow Analyzer
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: salinometer
type: salinometer
description: generic salinometer use salinometer when the instrument type used is unclear but the data include salinity measurements
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: temperature sensor
type: temperature sensor
description: A sensor used to measure temperature.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: titrator
type: titrator
description: titrator
platform: (MI_Platform)
identifier: (MD_Identifier)
code: BOSTON WHALER
description: BOSTON WHALER
instrument: (missing)
platform: (MI_Platform)
identifier: (MD_Identifier)
code: CCGS Beluga II
description: ICES request for for the vessel Beluga II from CANADA. Name : Beluga II Flag : CANADA - CA (ISO Country Code) Title : CCGS Platform Class : 37 Self-propelled boat Commissioned Date : 2011-03 Current Length : 9.45 Built : 2011 Confirmed by NOAA on 2013-05-22.
instrument: (missing)
platform: (MI_Platform)
identifier: (MD_Identifier)
code: CCGS M. Perley
description: Updated information from ICES for the vessel M. PERLEY from CANADA. Name : M. PERLEY Flag : CANADA - CA (ISO Country Code) Call Sign : CGMP Title : CCGS Platform Class : 31 Research vessel IMO : 9656151 Commissioned Date : 2012 Current Length : 22 Built : 2012 Notes : Nearshore Fishery Research Ship, near Coastal up to 200nm. MMSI 316022125 Additional Information Sources: - http://www.ccg-gcc.gc.ca/Fleet/Vessel?vessel_id=120 - http://www.marinetraffic.com/ais/shipdetails.aspx?mmsi=316022125 Submitted to ICES on 2013-07-16. Confirmed by NOAA on 2013-08-06.
instrument: (missing)
platform: (MI_Platform)
identifier: (MD_Identifier)
code: CCGS Teleost
description: Updated information from ICES for the vessel TELEOST from CANADA. Name : TELEOST Flag : CANADA - CA (ISO Country Code) Call Sign : CGCB Title : CCGS Platform Class : 31 Research vessel IMO : 8714346 Commissioned Date : 1995 Current Length : 63 Built : 1988 Previous Name (Notes): Atlantic Champion Notes : WOD code 7362. Built as an ice-reinforced factory freeze trawler, converted to function as a fisheries research platform suitable for the conduct of multi-function science missions in 1994. Additional Information Sources: - http://www.meds-sdmm.dfo-mpo.gc.ca/isdm-gdsi/azmp-pmza/docs/bulletin_2_11.pdf General Comments: IMO for TELEOST from Miramar Ship Index
instrument: (missing)
platform: (MI_Platform)
identifier: (MD_Identifier)
code: CORIOLIS II
description: Updated information from ICES for the vessel Coriolis II from CANADA. Name : Coriolis II Flag : CANADA - CA (ISO Country Code) Call Sign : CGDN Platform Class : 31 Research vessel IMO : 8818570 Commissioned Date : 2002 Current Length : 49.95 Built : 1991 Previous Name (Notes): CCGS John Jacobson Notes : WOD 8803. Originally called CCGS 501 (1991-1992). In addition to research and teaching, the very versatile Coriolis II can be used on location for various other ocean-related projects. Additional Information Sources: - http://www.ic.gc.ca/eic/site/696.nsf/fra/00861.html - http://en.wikipedia.org/wiki/RV_Coriolis_II - http://www.marinetraffic.com/ais/shipdetails.aspx?mmsi=316133000 General Comments: We have been using 18OL nationally and internationally for this ship, since 2003.
instrument: (missing)
platform: (MI_Platform)
identifier: (MD_Identifier)
code: HUDSON
description: HUDSON
instrument: (missing)
platform: (MI_Platform)
identifier: (MD_Identifier)
code: MARTHA L. BLACK
description: MARTHA L. BLACK
instrument: (missing)
