High-resolution ocean and atmosphere pCO2 time-series measurements from mooring CoastalLA_91W_30N in the Coastal Waters of Louisiana and Gulf of Mexico (NCEI Accession 0209137)
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abstract: This dataset includes chemical, meteorological, physical and time series data collected from Mooring CoastalLA_91W_30N in the Coastal Waters of Louisiana and Gulf of Mexico from 2017-07-14 to 2021-08-25. These data include air-sea difference - partial pressure of carbon dioxide (pCO2), barometric pressure, oxygen, pCO2 - atmosphere, pCO2 - water, salinity, sea surface temperature, oxygen, pH on total scale, total chlorophyll, nephelometric turbidity unit and salinity-compensated dissolved oxygen. The Moored Autonomous pCO2 [MAPCO2 (trademark of NOAA)] instruments used to collect these data include Bubble type equilibrator for autonomous carbon dioxide (CO2) measurement, Carbon dioxide (CO2) gas analyzer, Humidity Sensor, and oxygen meter. The Global CO2 Time-series and Moorings Project involves international groups from 18 countries who have mounted sensors on moored buoys to provide high resolution time-series measurements of atmospheric boundary layer and surface ocean CO2 partial pressure (pCO2). The CO2 Time-series and Moorings Project is coordinated by UNESCO International Ocean Carbon Coordination Project (IOCCP). The coastal LA buoy is located in 20 m water depth on the Louisiana continental shelf. The northern Gulf of Mexico has extensive wetlands and supports high biological diversity and biomass of fish, shellfish, and sea birds. This region is also the largest zone of oxygen-depleted (or hypoxic) coastal waters in the United States, which makes this region a unique setting to track the combined impacts of ocean acidification (OA) and hypoxia on the biological system. Coastal LA was established in July 2017 in collaboration with Dr. Stephan Howden from the University of Southern Mississippi after being previously deployed off coastal Mississippi. The move to the new location provides better coordination with long-term hypoxia monitoring projects and more opportunities for leveraging research on both hypoxia and OA. The OA observations at coastal LA are supported by NOAA's Ocean Acidification Program and also leveraged by existing activities supported through the Louisiana Universities Marine Consortium (LUMCON) and the Gulf of Mexico Coastal Ocean Observing System (GCOOS).
purpose: This dataset is available to the public for a wide variety of uses including scientific research and analysis.
credit: Funding Information: NOAA Ocean Acidification Program (PMEL Sustained Ocean Acidification Mooring Observations (PMO), 20895)
credit: Funding Information: NOAA Ocean Acidification Program (PMEL Sustained OA Data Management (PDM), 20845)
credit: Funding Information: NOAA Ocean Acidification Program (Sustained Ocean Acidification Data Management Quality Control Access and Products (Sutton PMEL), 17907)
credit: Funding Information: NOAA Ocean Acidification Program (Sustained Ocean Acidification Mooring Observations (Sutton PMEL), 17906)
credit: Funding Information: NOAA Ocean Acidification Program (PMEL FY2015–FY2017 NOAA Ocean Acidification Observing Network (NOA-ON) Sustained Investment Workplan: PMEL Sustained Ocean Acidification Mooring Observations (Sutton), OAP1506-1001)
credit: Funding Information: NOAA Ocean Acidification Program (PMEL Data Management Quality Control Access and Products, 13432)
credit: Funding Information: NOAA
credit: Funding Information: NOAA Climate Program
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description: Parameter or Variable: xCO2 SW (wet); Abbreviation: xCO2 SW (wet); Unit: (μmol/mol) Mole fraction of CO2 in air in equilibrium with the seawater at sea surface temperature and measured humidity.; Controlled vocabulary name: partial pressure of carbon dioxide - water; In-situ / Manipulation / Response variable: in-situ; Sampling instrument: MAPCO2 (trademark of NOAA).
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description: Parameter or Variable: Licor Atm Pressure; Abbreviation: Licor Atm Pressure; Unit: (hPa) Atmospheric pressure at the airblock, 4 feet above the sea surface.; Controlled vocabulary name: BAROMETRIC PRESSURE; In-situ / Manipulation / Response variable: in-situ; Sampling instrument: MAPCO2 (trademark of NOAA).
processStep: (LE_ProcessStep)
description: Parameter or Variable: Licor Temp; Abbreviation: Licor Temp; Unit: (C) Temperature of the Infrared Licor 820 in degrees Celsius.; In-situ / Manipulation / Response variable: in-situ; Sampling instrument: MAPCO2 (trademark of NOAA).
processStep: (LE_ProcessStep)
description: Parameter or Variable: MAPCO2 %O2; Abbreviation: MAPCO2 %O2; Unit: The percent oxygen of the surface seawater divided by the percent oxygen of the atmosphere at 4 feet above the sea surface. Disclaimer: The oxygen measurement is made in the equilibrated air. We have found that the oxygen does not come to complete equilibrium so any rapid changes in oxygen do not get properly captured using this system. Therefore, we tend to use the oxygen data only as a qualitative sense of the biology. It is not a quantitative measure.; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SST; Abbreviation: SST; Unit: (C) Sea Surface Temperature.; Controlled vocabulary name: SEA SURFACE TEMPERATURE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Salinity; Abbreviation: Salinity; Unit: (PSU) Sea Surface Salinity.; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: xCO2 SW (dry); Abbreviation: xCO2 SW (dry); Unit: (μmol/mol) Mole fraction of CO2 in air in equilibrium with the seawater at sea surface temperature (dry air).; Controlled vocabulary name: partial pressure of carbon dioxide - water; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: xCO2 Air (dry); Abbreviation: xCO2 Air (dry); Unit: (μmol/mol) Mole fraction of CO2 in air at the airblock, 4 feet above the sea surface (dry air).; Controlled vocabulary name: Partial pressure (or fugacity) of carbon dioxide - atmosphere; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: fCO2 SW (sat); Abbreviation: fCO2 SW (sat); Unit: (uatm) Fugacity of CO2 in air in equilibrium with the seawater at sea surface temperature (100% humidity). Since the measurements are taken at the sea surface, warming calculations are not necessary.; Controlled vocabulary name: partial pressure of carbon dioxide - water; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: fCO2 Air (sat); Abbreviation: fCO2 Air (sat); Unit: (uatm) Fugacity of CO2 in air at the airblock, 4 feet above the sea surface (100% humidity).; Controlled vocabulary name: Partial pressure (or fugacity) of carbon dioxide - atmosphere; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: dfCO2; Abbreviation: dfCO2; Unit: Difference of the fugacity of the CO2 in seawater and the fugacity of the CO2 in air (fCO2 SW - fCO2 Air).; Controlled vocabulary name: AIR-SEA DIFFERENCE - PARTIAL PRESSURE (OR FUGACITY) OF CARBON DIOXIDE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: pCO2 SW (wet); Abbreviation: pCO2 SW (wet); Unit: (uatm) Partial Pressure of CO2 in air in equilibrium with the seawater at sea surface temperature (100% humidity); Controlled vocabulary name: partial pressure of carbon dioxide - water; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: pCO2 Air (wet); Abbreviation: pCO2 Air (wet); Unit: (uatm) Partial Pressure of CO2 in air at the airblock, 4 feet above the sea surface (100% humidity).; Controlled vocabulary name: Partial pressure (or fugacity) of carbon dioxide - atmosphere; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: dpCO2; Abbreviation: dpCO2; Unit: Difference of the partial pressure of CO2 in seawater and air (pCO2 SW - pCO2 Air; Controlled vocabulary name: AIR-SEA DIFFERENCE - PARTIAL PRESSURE (OR FUGACITY) OF CARBON DIOXIDE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Sea water pH on total scale; Abbreviation: pH SW; Unit: pH of Seawater (total scale); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: pH QF; Abbreviation: pH QF; Unit: Quality Flag for pH; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Total Chlorophyll; Abbreviation: CHL; Unit: ug/l; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Nephelometric Turbidity Unit (NTU Units); Abbreviation: NTU; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Salinity-Compensated dissolved oxygen; Abbreviation: DOXY; Unit: umol/kg; In-situ / Manipulation / Response variable: in-situ .
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metadataMaintenance: (MD_MaintenanceInformation)
maintenanceAndUpdateFrequency: (MD_MaintenanceFrequencyCode) asNeeded
maintenanceNote: Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.
maintenanceNote: NCEI Accession 0209137 was revised and a new version of the archival package was published. Updates to existing archival packages may provide additional files or replace obsolete files. The latest version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession. Please see journal.txt in the /about directory for additional details on changes made.
contact: (CI_ResponsibleParty)
organisationName: NOAA National Centers for Environmental Information
role: (CI_RoleCode) custodian
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acquisitionInformation: (MI_AcquisitionInformation)
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: bubble type equilibrator for autonomous carbon dioxide (CO2) measurement
type: bubble type equilibrator for autonomous carbon dioxide (CO2) measurement
description: This type of equilibrators are often used on buoys. Developed by Pacific Marine Environmental Laboratory and Monterey Bay Aquarium Research Institute, the h-shaped bubble equilibrator does not require a water pump to spray water from the top. see Takahashi 1961 for more information.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: carbon dioxide (CO2) gas analyzer
type: carbon dioxide (CO2) gas analyzer
description: measures gaseous carbon dioxide Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption. Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water. To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: humidity sensor
type: humidity sensor
description: HUMIDITY SENSORS are devices that receive a signal or stimulus (as heat or pressure or light or motion etc.) and responds to it, in this case humidity or some measure of the water vapor content of air.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: oxygen sensor
type: oxygen sensor
description: Any instrument that measures oxygen content in a compound.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: pH sensor
type: pH sensor
description: generic meter used to measure pH Any of a class of instruments used to quantify pH in a water or other type of sample.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: temperature sensor
type: temperature sensor
description: A sensor used to measure temperature.
platform: (MI_Platform)
identifier: (MD_Identifier)
code: moorings
description: entry created as MOORINGS OF UNITED STATES, but has been used as a generic MOORINGS entry.
instrument: (missing)