Gridded surface water fugacity of CO2 observations, and calculated pH, aragonite saturation state and air–sea CO2 fluxes in the northern Caribbean Sea from 2002 through 2019 (NCEI Accession 0207749)
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title: Gridded surface water fugacity of CO2 observations, and calculated pH, aragonite saturation state and air–sea CO2 fluxes in the northern Caribbean Sea from 2002 through 2019 (NCEI Accession 0207749)
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abstract: This dataset contains a high-quality dataset of derived products from over a million observations of surface water partial pressure/fugacity of carbon dioxide (pCO2w/fCO2w), for the Caribbean Sea, Gulf of Mexico and North-East Atlantic Ocean covering the timespan from 2003-03-01 to 2019-12-30. Prior to installation of automated pCO2 systems on cruise ships of the Royal Caribbean Cruise Lines and subsidiaries (Explorer of the Seas, Celebrity Equinox, Allure of the Seas), very limited surface water carbon data were available in this region. With this observational program, the Northern Caribbean Sea has now become one of the best sampled regions for pCO2 of the world's ocean. The derived quantities include total alkalinity (TA), acidity (pH), aragonite saturation state (ΩAr) and air-sea CO2 flux.
purpose: This dataset is available to the public for a wide variety of uses including scientific research and analysis.
credit: Funding Information: NOAA Climate Program Office; NOAA's Ocean Acidification Program (Quantifying sea-air CO2 fluxes using surface water pCO2 measurements from ships of opportunity, Ocean acidification Ship of Opportunity (SOOP))
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name: GCMD Keyword Forum Page
description: Global Change Master Directory (GCMD). 2023. GCMD Keywords, Version 18. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords
function: (CI_OnLineFunctionCode) information
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descriptiveKeywords: (MD_Keywords)
keyword:
Anchor: https://vocab.ices.dk/services/pox/GetCodeDetail/SHIPC/BHAF ALLURE OF THE SEAS (call sign: C6XS8, ICES code: BHAF, 2010)
keyword:
Anchor: https://vocab.ices.dk/services/pox/GetCodeDetail/SHIPC/MLCE Celebrity Equinox (call sign: 9HXD9, ICES code: MLCE)
type: (MD_KeywordTypeCode) platform
thesaurusName: (CI_Citation)
title: ICES/SeaDataNet Ship Codes
date: (inapplicable)
descriptiveKeywords: (MD_Keywords)
keyword:
Anchor: https://gcmd.earthdata.nasa.gov/kms/concept/a4202721-0cba-4fa1-853f-890f146b04f9 OCEAN > ATLANTIC OCEAN > NORTH ATLANTIC OCEAN
keyword:
Anchor: https://gcmd.earthdata.nasa.gov/kms/concept/eb176e48-13e2-413c-85d6-b37e16303573 OCEAN > ATLANTIC OCEAN > NORTH ATLANTIC OCEAN > CARIBBEAN SEA
keyword:
Anchor: https://gcmd.earthdata.nasa.gov/kms/concept/75fab119-51a6-4b59-9711-f6c3cd3139db OCEAN > ATLANTIC OCEAN > NORTH ATLANTIC OCEAN > GULF OF MEXICO
type: (MD_KeywordTypeCode) place
thesaurusName: (CI_Citation)
title: Global Change Master Directory (GCMD) Location Keywords
date: (CI_Date)
date: 2023
dateType: (CI_DateTypeCode) revision
edition: 18
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organisationName: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA)
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city: Greenbelt
administrativeArea: MD
onlineResource: (CI_OnlineResource)
linkage: https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords
protocol: HTTPS
name: GCMD Keyword Forum Page
description: Global Change Master Directory (GCMD). 2023. GCMD Keywords, Version 18. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords
function: (CI_OnLineFunctionCode) information
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descriptiveKeywords: (MD_Keywords)
keyword: Atlantic Ocean
keyword: Caribbean Sea
keyword: Gulf of Mexico
type: (MD_KeywordTypeCode) place
thesaurusName: (CI_Citation)
title: Provider Geographic Names
date: (inapplicable)
resourceConstraints: (MD_Constraints)
useLimitation: accessLevel: Public
resourceConstraints: (MD_LegalConstraints)
useConstraints: (MD_RestrictionCode) otherRestrictions
otherConstraints: Cite as: Wanninkhof, Rik; Pierrot, Denis; Sullivan, Kevin F.; Barbero, Leticia; Triñanes, Joaquin A. (2019). Gridded surface water fugacity of CO2 observations, and calculated pH, aragonite saturation state and air–sea CO2 fluxes in the northern Caribbean Sea from 2002 through 2019 (NCEI Accession 0207749). [indicate subset used]. NOAA National Centers for Environmental Information. Dataset. https://doi.org/10.25921/2swk-9w56. Accessed [date].
resourceConstraints: (MD_LegalConstraints)
useLimitation: Distribution liability: NOAA and NCEI make no warranty, expressed or implied, regarding these data, nor does the fact of distribution constitute such a warranty. NOAA and NCEI cannot assume liability for any damages caused by any errors or omissions in these data. If appropriate, NCEI can only certify that the data it distributes are an authentic copy of the records that were accepted for inclusion in the NCEI archives.
resourceConstraints: (MD_LegalConstraints)
accessConstraints: (MD_RestrictionCode) otherRestrictions
otherConstraints: Use liability: NOAA and NCEI cannot provide any warranty as to the accuracy, reliability, or completeness of furnished data. Users assume responsibility to determine the usability of these data. The user is responsible for the results of any application of this data for other than its intended purpose.
aggregationInfo: (MD_AggregateInformation)
aggregateDataSetName: (CI_Citation)
title: Wanninkhof, R., Pierrot, D., Sullivan, K., Barbero, L., and Triñanes, J. (2020). A 17-year dataset of surface water fugacity of CO2 along with calculated pH, aragonite saturation state and air-sea CO2 fluxes in the northern Caribbean Sea. Earth Syst. Sci. Data, 12(3), 1489-1509. https://essd.copernicus.org/articles/12/1489/2020/
date: (CI_Date)
date: 2020
dateType: (CI_DateTypeCode) publication
citedResponsibleParty: (CI_ResponsibleParty)
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linkage: https://essd.copernicus.org/articles/12/1489/2020/
protocol: HTTPS
name: https://essd.copernicus.org/articles/12/1489/2020/
description: related publication or dataset
function: (CI_OnLineFunctionCode) information
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associationType: (DS_AssociationTypeCode) crossReference
initiativeType: (DS_InitiativeTypeCode) project
aggregationInfo: (MD_AggregateInformation)
aggregateDataSetName: (CI_Citation)
title: Cruise Ships Explorer of the Seas, Celebrity Equinox, Allure of the Seas Lines
date: (CI_Date)
date: 2022
dateType: (CI_DateTypeCode) publication
citedResponsibleParty: (CI_ResponsibleParty)
positionName: (unknown)
contactInfo: (CI_Contact)
onlineResource: (CI_OnlineResource)
linkage: https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/explorer.html
protocol: HTTPS
name: https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/VOS_Program/explorer.html
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function: (CI_OnLineFunctionCode) information
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citedResponsibleParty: (CI_ResponsibleParty)
organisationName:
Anchor: https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 US DOC; NOAA; NESDIS; National Centers for Environmental Information (NCEI)
role: (CI_RoleCode) publisher
presentationForm: (CI_PresentationFormCode) documentDigital
associationType: (DS_AssociationTypeCode) crossReference
initiativeType: (DS_InitiativeTypeCode) project
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aggregateDataSetName: (CI_Citation)
title: NOAA National Centers for Environmental Information (2022). Ocean Carbon and Acidification Data System (OCADS). NOAA National Centers for Environmental Information. https://www.ncei.noaa.gov/products/ocean-carbon-acidification-data-system
date: (CI_Date)
date: 2022-04
dateType: (CI_DateTypeCode) publication
citedResponsibleParty: (CI_ResponsibleParty)
positionName: (unknown)
contactInfo: (CI_Contact)
onlineResource: (CI_OnlineResource)
linkage: https://www.ncei.noaa.gov/products/ocean-carbon-acidification-data-system
protocol: HTTPS
name: https://www.ncei.noaa.gov/products/ocean-carbon-acidification-data-system
description: OCADS website
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Anchor: https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 NOAA National Centers for Environmental Information
role: (CI_RoleCode) author
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Anchor: https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 US DOC; NOAA; NESDIS; National Centers for Environmental Information (NCEI)
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otherCitationDetails: [accessed 2024-02-08]
associationType: (DS_AssociationTypeCode) crossReference
initiativeType: (DS_InitiativeTypeCode) program
language:
LanguageCode: eng; USA
characterSet: (MD_CharacterSetCode) utf8
topicCategory: (MD_TopicCategoryCode) environment
topicCategory: (MD_TopicCategoryCode) oceans
extent: (EX_Extent)
geographicElement: (EX_GeographicBoundingBox)
westBoundLongitude: -88.5
eastBoundLongitude: -60.5
southBoundLatitude: 15.5
northBoundLatitude: 29.5
temporalElement: (EX_TemporalExtent)
extent:
TimePeriod:
beginPosition: 2003-03-01
endPosition: 2019-12-30
supplementalInformation: In this accession, NCEI has archived multiple versions of these data. The latest (and best) version of these data has the largest version number.
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distributionInfo: (MD_Distribution)
distributor: (MD_Distributor)
distributorContact: (CI_ResponsibleParty)
organisationName:
Anchor: https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1730 NOAA National Centers for Environmental Information
contactInfo: (CI_Contact)
phone: (CI_Telephone)
voice: +1-301-713-3277
address: (CI_Address)
electronicMailAddress: NCEI.Info@noaa.gov
role: (CI_RoleCode) pointOfContact
distributionOrderProcess: (MD_StandardOrderProcess)
fees: In most cases, electronic downloads of the data are free. However, fees may apply for custom orders, data certifications, copies of analog materials, and data distribution on physical media.
orderingInstructions: Contact NCEI for other distribution options and instructions.
distributorFormat: (MD_Format)
name: Originator data format
version: (unknown)
distributorTransferOptions: (MD_DigitalTransferOptions)
transferSize:
Real: 23.148
onLine: (CI_OnlineResource)
linkage: https://www.ncei.noaa.gov/data/oceans/ncei/ocads/metadata/0207749.html
protocol: HTTPS
applicationProfile: Web browser
name: Project Metadata
description: Navigate directly to the URL for a descriptive web page with download links.
function: (CI_OnLineFunctionCode) information
onLine: (CI_OnlineResource)
linkage: https://doi.org/10.25921/2swk-9w56
protocol: HTTPS
applicationProfile: Web browser
name: NCEI Dataset Landing Page
description: Navigate directly to the URL for a descriptive web page with download links.
function: (CI_OnLineFunctionCode) information
onLine: (CI_OnlineResource)
linkage: https://www.ncei.noaa.gov/archive/accession/oas/207749
protocol: HTTPS
applicationProfile: Web browser
name: Descriptive Information
description: Navigate directly to the URL for a descriptive web page with download links.
function: (CI_OnLineFunctionCode) information
onLine: (CI_OnlineResource)
linkage: https://www.ncei.noaa.gov/archive/accession/download/207749
protocol: HTTPS
applicationProfile: Web browser
name: HTTPS
description: Navigate directly to the URL for data access and direct download.
function: (CI_OnLineFunctionCode) download
onLine: (CI_OnlineResource)
linkage: ftp://ftp-oceans.ncei.noaa.gov/nodc/archive/arc0151/0207749/
protocol: FTP
applicationProfile: Any FTP client
name: FTP
description: These data are available through the File Transfer Protocol (FTP). FTP is no longer supported by most internet browsers. You may copy and paste the FTP link to the data into an FTP client (e.g., FileZilla or WinSCP).
function: (CI_OnLineFunctionCode) download
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dataQualityInfo: (DQ_DataQuality)
scope: (DQ_Scope)
level: (MD_ScopeCode) dataset
lineage: (LI_Lineage)
processStep: (LE_ProcessStep)
description: NCEI Accession 0207749 v1.1 was published.
dateTime:
DateTime: 2019-12-20T19:48:14Z
output: (LE_Source)
sourceCitation: (CI_Citation)
title: NCEI Accession 0207749 v1.1
date: (CI_Date)
date: (inapplicable)
dateType: (CI_DateTypeCode) publication
citedResponsibleParty: (CI_ResponsibleParty)
individualName: (inapplicable)
contactInfo: (CI_Contact)
onlineResource: (CI_OnlineResource)
linkage: https://www.ncei.noaa.gov/archive/accession/0207749/1.1
protocol: HTTPS
name: NCEI Accession 0207749 v1.1
description: published 2019-12-20T19:48:14Z
function: (CI_OnLineFunctionCode) download
role: (inapplicable)
processStep: (LE_ProcessStep)
description: NCEI Accession 0207749 was revised and v2.2 was published.
rationale: Updates were received for this dataset. These updates were copied into the data/0-data/ directory of this accession. These updates may provide additional files or replace obsolete files. This version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession.
dateTime:
DateTime: 2020-08-28T19:46:59Z
output: (LE_Source)
sourceCitation: (CI_Citation)
title: NCEI Accession 0207749 v2.2
date: (CI_Date)
date: (inapplicable)
dateType: (CI_DateTypeCode) publication
citedResponsibleParty: (CI_ResponsibleParty)
individualName: (inapplicable)
contactInfo: (CI_Contact)
onlineResource: (CI_OnlineResource)
linkage: https://www.ncei.noaa.gov/archive/accession/0207749/2.2
protocol: HTTPS
name: NCEI Accession 0207749 v2.2
description: published 2020-08-28T19:46:59Z
function: (CI_OnLineFunctionCode) download
role: (inapplicable)
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dataQualityInfo: (DQ_DataQuality)
scope: (DQ_Scope)
level: (MD_ScopeCode) dataset
lineage: (LI_Lineage)
processStep: (LE_ProcessStep)
description: Parameter or Variable: Year of measurements used for calculations; Abbreviation: Year.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Month of measurements used for calculations: 1 (January) through 12 (December); Abbreviation: Month.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Latitude. North is positive. Location is the center point of the grid. That is, 15.5˚ N is the grid box spanning 15˚ N to 16˚ N; Abbreviation: Lat; Unit: Degrees.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Longitude. East is positive. All values in the Caribbean are negative. Location is center point of grid. That is, -87.5 is the grid box spanning 87˚ W to 88˚ W; Abbreviation: Lon; Unit: Degrees.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Area of grid box excluding land where appropriate; Abbreviation: Area; Unit: Km2.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Number of fCO2w observations in the particular grid box for the particular month; Abbreviation: #_Obs.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Sea surface temperature measured at the intake (average of the grid box); Abbreviation: SST_OBS; Unit: ˚C.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Standard deviation of SST; Abbreviation: SST_STD; Unit: ˚C.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Sea surface salinity measured by thermosalinograph (average of the grid box); Abbreviation: SSS_OBS; Unit: permil.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Standard deviation of SSS; Abbreviation: SSS_STD.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Fugacity of CO2 in seawater (average of the grid box); Abbreviation: fCO2w_OBS; Unit: µatm.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Standard deviation of fCO2w observations in the grid box; Abbreviation: fCO2w_STDEV.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Total alkalinity calculated from a relationship salinity TA = 57.3SSS_OBS+ 296.4 (Cai et al., 2010) using the measured SSS; Abbreviation: TA; Unit: µmol kg-1.
processStep: (LE_ProcessStep)
description: Parameter or Variable: pH on the total scale at SST calculated from fCO2w_OBS and TA using the CO2SYS program of Pierrot et al. (2006) with pH Scale: Total scale (mol/kg-SW) at OISST; CO2 Constants: K1, K2 from Lueker et al. (2000); KSO4- for Dickson (1990); KF from Perez and Fraga (1987) and Total Boron from Uppström (1974); Abbreviation: pHT.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Aragonite saturation state calculated using CO2SYS with fCO2w_OBS and TA as input parameters and the same dissociation constants as used for pHT; Abbreviation: ΩAr.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Optimal interpolated sea surface temperature (Reynolds et al., 2007) for the particular grid box; Abbreviation: OISST; Unit: ˚C.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Sea surface salinity from the HYCOM model; Abbreviation: SSSHYCOM; Unit: permil.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Fugacity of CO2 in seawater determined from annual MLRs (see Table 1) with Lat, Lon, SST, OISST, SSSHYCOM, and MLDHYCOM.; Abbreviation: fCO2w_MLR; Unit: µatm.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Fugacity of CO2 in air using the average value between atmospheric sampling station KEY and RBP; Abbreviation: fCO2a; Unit: µatm.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Air-water fugacity difference, fCO2w - fCO2a; Abbreviation: ∆fCO2; Unit: µatm.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Second moment of the wind based on ¼˚ 6-h CCMP-2 product (Atlas et al., 2011); Abbreviation: u2; Unit: m2 s-2.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Monthly air-sea CO2 flux calculated according to Eqs. 4 and 5; Abbreviation: CO2_Flux; Unit: mol m-2 mo-1.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Total monthly air-sea CO2 flux calculated according to Eqs. 4 and 5 in Teragram carbon; Abbreviation: CO2_FluxTotal; Unit: Tg C mo-1 .
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metadataMaintenance: (MD_MaintenanceInformation)
maintenanceAndUpdateFrequency: (MD_MaintenanceFrequencyCode) asNeeded
maintenanceNote: Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.
maintenanceNote: NCEI Accession 0207749 was revised and a new version of the archival package was published. Updates to existing archival packages may provide additional files or replace obsolete files. The latest version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession. Please see journal.txt in the /about directory for additional details on changes made.
contact: (CI_ResponsibleParty)
organisationName: NOAA National Centers for Environmental Information
role: (CI_RoleCode) custodian
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acquisitionInformation: (MI_AcquisitionInformation)
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: showerhead equilibrator
type: showerhead equilibrator
description: extracts dissolved CO2 from water A carbon dioxide equilibrator is usually in the shape of a vertical tube, with a showerhead on the top, some headspace, a lot of beads to increase the surface exchange area between water and air, a water seal device at the bottom to allow water to overflow, but prevents air exchange between inside and outside. Carbon dioxide (CO2) equilibrator works together with carbon dioxide (CO2) gas analyzer (insttypes_id 183) to measure carbon dioxide in the water. To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.
platform: (MI_Platform)
identifier: (MD_Identifier)
code: Allure Of The Seas
description: Updated information from ICES for the vessel ALLURE OF THE SEAS from BAHAMAS(BS). Name : ALLURE OF THE SEAS Country(s) : BAHAMAS(BS) (ISO Country Code) Platform Class : 32 Vessel of opportunity Call Sign : C6XS8 MMSI: 311020700 IMO : 9383948 Commissioned Date : 2010 Current Length : 362 Built : 2010-11-20 WOD Code: 10940 Notes : Passenger Ship. Information Sources: - http://www.largestships.com/ms-allure-of-the-seas/ - http://www.shipspotting.com/gallery/photo.php?lid=1365173 - http://www.marinetraffic.com/ais/details/ships/shipid:372814/mmsi:311020700/imo:9383948/vessel:ALLURE_OF_THE_SEAS General Comments: Confirmed in Miramar Ship Index Confirmed by NOAA on 2015-08-25. Submitted to ICES 2015-04-30.
instrument: (missing)
platform: (MI_Platform)
identifier: (MD_Identifier)
code: Celebrity Equinox
description: ICES request for the vessel Celebrity Equinox from MALTA(MT). Name : Celebrity Equinox Country(s) : MALTA(MT) (ISO Country Code) Call Sign : 9HXD9 MMSI: 249667000 IMO : 9372456 Current Length : 317 Built : 2009-07-16 Information Sources: - http://www.shipspotting.com/gallery/photo.php?lid=2212906 - http://www.fleetmon.com/en/vessels/Celebrity_Equinox_63127/photos/815254 General Comments: IMO for Celebrity Equinox confirmed in Miramar Ship Index Confirmed by NOAA on 2015-08-25.
instrument: (missing)
platform: (MI_Platform)
identifier: (MD_Identifier)
code: EXPLORER OF THE SEAS
description: Flag: Bahamas Vessel Type: Cruise Ship DOB: Sep 2000 IMO: 9161728 Former Call Sign: ELWX5 Royal Caribbean International
instrument: (missing)
