Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, Barometric pressure sensor and other instruments from NOAA Ship RONALD H. BROWN in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2005-01-11 to 2005-02-24 (NCEI Accession 0108153)
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title: Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, Barometric pressure sensor and other instruments from NOAA Ship RONALD H. BROWN in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2005-01-11 to 2005-02-24 (NCEI Accession 0108153)
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abstract: This dataset includes discrete sample and profile data collected from NOAA Ship RONALD H. BROWN in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans (> 60 degrees South) from 2005-01-11 to 2005-02-24 and retrieved during cruise CLIVAR_A16S_2005. These data include AIR TEMPERATURE, AIR-SEA DIFFERENCE - PARTIAL PRESSURE (OR FUGACITY) OF CARBON DIOXIDE, BAROMETRIC PRESSURE, CHLOROFLUOROCARBON-11 (CFC-11), CHLOROFLUOROCARBON-113 (CFC-113), CHLOROFLUOROCARBON-12 (CFC-12), Carbon tetrachloride (CCL4), Chromophoric Dissolved Organic Matter (CDOM), DELTA CARBON-13, DELTA CARBON-14, DELTA HELIUM-3, DISSOLVED INORGANIC CARBON (DIC), DISSOLVED ORGANIC CARBON, DISSOLVED OXYGEN, FLUORESCENCE, HELIUM, HYDROSTATIC PRESSURE, NEON, NITRATE, NITRITE, Partial pressure (or fugacity) of carbon dioxide - atmosphere, Partial pressure (or fugacity) of carbon dioxide - water, SALINITY, SEA SURFACE TEMPERATURE, TOTAL ALKALINITY (TA), Tritium (Hydrogen isotope), WATER TEMPERATURE, WIND DIRECTION, WIND SPEED, pH, phosphate and silicate. The instruments used to collect these data include Alkalinity titrator, Barometric pressure sensor, CTD, Carbon dioxide (CO2) gas analyzer, Coulometer for DIC measurement, Flask with closed headspace for discrete carbon dioxide (CO2) measurement, bottle, spectrophotometer and thermosalinographs. These data were collected by Frank J. Millero of Rosenstiel School of Marine and Atmospheric Science, Rik Wanninkhof of NOAA Atlantic Oceanographic and Meteorological Laboratory and Richard A. Feely of US DOC; NOAA; OAR; Pacific Marine Environmental Laboratory as part of the CLIVAR_A16S_2005 data set. The International CLIVAR Global Ocean Carbon and Repeat Hydrography Program carries out a systematic and global re-occupation of select WOCE/JGOFS hydrographic sections to quantify changes in storage and transport of heat, fresh water, carbon dioxide (CO2), and related parameters.
purpose: This dataset is available to the public for a wide variety of uses including scientific research and analysis.
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linkage: https://www.ncei.noaa.gov/data/oceans/ncei/ocads/metadata/0108153.html
protocol: HTTPS
applicationProfile: Web browser
name: Project Metadata
description: Navigate directly to the URL for a descriptive web page with download links.
function: (CI_OnLineFunctionCode) information
onLine: (CI_OnlineResource)
linkage: https://doi.org/10.3334/cdiac/otg.ndp087
protocol: HTTPS
applicationProfile: Web browser
name: NCEI Dataset Landing Page
description: Navigate directly to the URL for a descriptive web page with download links.
function: (CI_OnLineFunctionCode) information
onLine: (CI_OnlineResource)
linkage: https://www.ncei.noaa.gov/archive/accession/oas/108153
protocol: HTTPS
applicationProfile: Web browser
name: Descriptive Information
description: Navigate directly to the URL for a descriptive web page with download links.
function: (CI_OnLineFunctionCode) information
onLine: (CI_OnlineResource)
linkage: https://www.ncei.noaa.gov/archive/accession/download/108153
protocol: HTTPS
applicationProfile: Web browser
name: HTTPS
description: Navigate directly to the URL for data access and direct download.
function: (CI_OnLineFunctionCode) download
onLine: (CI_OnlineResource)
linkage: ftp://ftp-oceans.ncei.noaa.gov/nodc/archive/arc0057/0108153/
protocol: FTP
applicationProfile: Any FTP client
name: FTP
description: These data are available through the File Transfer Protocol (FTP). FTP is no longer supported by most internet browsers. You may copy and paste the FTP link to the data into an FTP client (e.g., FileZilla or WinSCP).
function: (CI_OnLineFunctionCode) download
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dataQualityInfo: (DQ_DataQuality)
scope: (DQ_Scope)
level: (MD_ScopeCode) dataset
lineage: (LI_Lineage)
processStep: (LE_ProcessStep)
description: NCEI Accession 0108153 v1.1 was published.
dateTime:
DateTime: 2013-06-07T19:42:08Z
output: (LE_Source)
sourceCitation: (CI_Citation)
title: NCEI Accession 0108153 v1.1
date: (CI_Date)
date: (inapplicable)
dateType: (CI_DateTypeCode) publication
citedResponsibleParty: (CI_ResponsibleParty)
individualName: (inapplicable)
contactInfo: (CI_Contact)
onlineResource: (CI_OnlineResource)
linkage: https://www.ncei.noaa.gov/archive/accession/0108153/1.1
protocol: HTTPS
name: NCEI Accession 0108153 v1.1
description: published 2013-06-07T19:42:08Z
function: (CI_OnLineFunctionCode) download
role: (inapplicable)
processStep: (LE_ProcessStep)
description: NCEI Accession 0108153 was revised and v2.2 was published.
rationale: Updates were received for this dataset. These updates were copied into the data/0-data/ directory of this accession. These updates may provide additional files or replace obsolete files. This version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession.
dateTime:
DateTime: 2014-06-03T18:37:09Z
output: (LE_Source)
sourceCitation: (CI_Citation)
title: NCEI Accession 0108153 v2.2
date: (CI_Date)
date: (inapplicable)
dateType: (CI_DateTypeCode) publication
citedResponsibleParty: (CI_ResponsibleParty)
individualName: (inapplicable)
contactInfo: (CI_Contact)
onlineResource: (CI_OnlineResource)
linkage: https://www.ncei.noaa.gov/archive/accession/0108153/2.2
protocol: HTTPS
name: NCEI Accession 0108153 v2.2
description: published 2014-06-03T18:37:09Z
function: (CI_OnLineFunctionCode) download
role: (inapplicable)
processStep: (LE_ProcessStep)
description: NCEI Accession 0108153 was revised and v3.3 was published.
rationale: Updates were received for this dataset. These updates were copied into the data/0-data/ directory of this accession. These updates may provide additional files or replace obsolete files. This version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession.
dateTime:
DateTime: 2016-02-21T20:26:20Z
output: (LE_Source)
sourceCitation: (CI_Citation)
title: NCEI Accession 0108153 v3.3
date: (CI_Date)
date: (inapplicable)
dateType: (CI_DateTypeCode) publication
citedResponsibleParty: (CI_ResponsibleParty)
individualName: (inapplicable)
contactInfo: (CI_Contact)
onlineResource: (CI_OnlineResource)
linkage: https://www.ncei.noaa.gov/archive/accession/0108153/3.3
protocol: HTTPS
name: NCEI Accession 0108153 v3.3
description: published 2016-02-21T20:26:20Z
function: (CI_OnLineFunctionCode) download
role: (inapplicable)
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dataQualityInfo: (DQ_DataQuality)
scope: (DQ_Scope)
level: (MD_ScopeCode) dataset
lineage: (LI_Lineage)
processStep: (LE_ProcessStep)
description: Parameter or Variable: Dissolved Inorganic Carbon; Abbreviation: DIC; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Calculated; Replicate information: 180 duplicates out of 2482 samples taken during cruise; Standardization description: gas loops and CRM's; CRM batch number: #66.
processStep: (LE_ProcessStep)
description: Parameter or Variable: Total alkalinity; Abbreviation: TA; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Type of titration: The method utilizes a multi-point hydrochloric acid titration of seawater according to the definition of total alkalinity (Dickson, 1981).; Cell type (open or closed): Closed; Curve fitting method: The titration system used consists of a Metrohm 665 Dosimat titrator, an Orion 720A pH meter and a custom designed plastic water-jacketed titration cell (Millero et al., 1993b).; Uncertainty: CRM: Standard Deviation: ± 3.5 µmol/kg Duplicates: Instrument 1: ± 1.6 µmol/kg Instrument 2: ± 1.3 µmol/kg Between Systems: ± 2.9 µmol/kg; Method reference: Millero, F.J., J.-Z. Zhang, K, Lee, and D.M. Campbell, 1993b: Titration alkalinity of seawater. Mar. Chem., v. 44, pp. 153-165..
processStep: (LE_ProcessStep)
description: Parameter or Variable: pH; Abbreviation: pH; pH scale: Sea Water Scale (SWS); Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Temperature of pH measurement: 25C; Detailed sampling and analyzing information: Measurements of the pH of seawater on the total hydrogen ion concentration pH scale (pHt) were made using the multi-wavelength spectrophotometric techniques of Clayton and Byrne (1993).; Uncertainty: A precision of better than 0.001. Batch #59: pHsws @ 25C 7.9048 +/- 0.0007 (n = 19).
processStep: (LE_ProcessStep)
description: Parameter or Variable: pCO2 (fCO2) discrete; Abbreviation: fCO2; Observation type: discrete; In-situ / Manipulation / Response variable: In-situ observation; Measured or calculated: Measured; Storage method: Poisoned with 0.3 ml HgCl2 and stored upside down in coolers up to 12-hours; Seawater volume: 500 mL in a volumetric flask; Headspace volume: 120 mL; Temperature of measurement: 20deg.C; Detailed sampling and analyzing information: Headspace analysis using a LICOR infrared analyzer; Sample replicate information: 0.2+/- 0.2% or 2.3 +/- 1.5 ppm (n=90); Temperature correction method: waterbath was always within 0.03 C from 20 C. The small correction to 20 C was done by dpCO2/dt = 0.0423; Uncertainty: Internal consistency calculations with DIC and TAlk showed TAlk-measured-Talk(DIC,fCO2) of -2 and a st dev of 4.1 μmol/kg (n=768). If error is distributed evely between all parameters the fCO2 accuracy would be about 3 uatm.; Method reference: Wanninkhof and Thoning (1993).
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDTMP; Abbreviation: CTDTMP; Unit: DEG_C; Controlled vocabulary name: WATER TEMPERATURE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDSAL; Abbreviation: CTDSAL; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SALNTY; Abbreviation: SALNTY; Controlled vocabulary name: SALINITY; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CTDOXY; Abbreviation: CTDOXY; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: OXYGEN; Abbreviation: OXYGEN; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED OXYGEN; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: SILCAT; Abbreviation: SILCAT; Unit: UMOL/KG; Controlled vocabulary name: silicate; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: NITRAT; Abbreviation: NITRAT; Unit: UMOL/KG; Controlled vocabulary name: NITRATE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: NITRIT; Abbreviation: NITRIT; Unit: UMOL/KG; Controlled vocabulary name: NITRITE; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: PHSPHT; Abbreviation: PHSPHT; Unit: UMOL/KG; Controlled vocabulary name: phosphate; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CFC-11; Abbreviation: CFC-11; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-11 (CFC-11); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CFC-12; Abbreviation: CFC-12; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-12 (CFC-12); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CFC113; Abbreviation: CFC113; Unit: PMOL/KG; Controlled vocabulary name: CHLOROFLUOROCARBON-113 (CFC-113); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: CCL4; Abbreviation: CCL4; Unit: PMOL/KG; Controlled vocabulary name: Carbon tetrachloride (CCL4); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: PCO2; Abbreviation: PCO2; Unit: UATM; Controlled vocabulary name: partial pressure of carbon dioxide - water; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: PH; Abbreviation: PH; Unit: SWS@25C; Controlled vocabulary name: pH; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: ALKALI; Abbreviation: ALKALI; Unit: UMOL/KG; Controlled vocabulary name: total alkalinity; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: TCARBN; Abbreviation: TCARBN; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED INORGANIC CARBON (DIC); In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: DOC; Abbreviation: DOC; Unit: UMOL/KG; Controlled vocabulary name: DISSOLVED ORGANIC CARBON; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: DELC14; Abbreviation: DELC14; Unit: /MILLE; Controlled vocabulary name: DELTA CARBON-14; In-situ / Manipulation / Response variable: in-situ.
processStep: (LE_ProcessStep)
description: Parameter or Variable: C14ERR; Abbreviation: C14ERR; Unit: /MILLE; In-situ / Manipulation / Response variable: in-situ .
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dataQualityInfo: (DQ_DataQuality)
scope: (DQ_Scope)
level: (MD_ScopeCode) repository
levelDescription: (MD_ScopeDescription)
other: NOAA National Centers for Environmental Information
lineage: (LI_Lineage)
processStep: (LE_ProcessStep)
description: NOAA created the National Centers for Environmental Information (NCEI) by merging NOAA's National Climatic Data Center (NCDC), National Geophysical Data Center (NGDC), and National Oceanographic Data Center (NODC), including the National Coastal Data Development Center (NCDDC), per the Consolidated and Further Continuing Appropriations Act, 2015, Public Law 113-235. NCEI launched publicly on April 22, 2015.
dateTime:
DateTime: 2015-04-22T00:00:00
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metadataMaintenance: (MD_MaintenanceInformation)
maintenanceAndUpdateFrequency: (MD_MaintenanceFrequencyCode) asNeeded
maintenanceNote: Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.
maintenanceNote: NCEI Accession 0108153 was revised and a new version of the archival package was published. Updates to existing archival packages may provide additional files or replace obsolete files. The latest version contains the most complete and up-to-date representation of this archival information package. All of the files received prior to this update are available in the preceding version of this accession. Please see journal.txt in the /about directory for additional details on changes made.
contact: (CI_ResponsibleParty)
organisationName: NOAA National Centers for Environmental Information
role: (CI_RoleCode) custodian
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acquisitionInformation: (MI_AcquisitionInformation)
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: barometric pressure sensor
type: barometric pressure sensor
description: instrument used to measure the atmospheric pressure.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: bottle
type: bottle
description: any type of water bottle sampling device Generic name for water collection device; usually used to determine temperature, salinity and provide water aliquots for measurement of a wide range of parameters; often referred to by a specific type of water sampling bottle, such as a Nansen or Niskin bottle.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: carbon dioxide (CO2) gas analyzer
type: carbon dioxide (CO2) gas analyzer
description: measures gaseous carbon dioxide Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption. Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water. To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: coulometer for DIC measurement
type: coulometer for DIC measurement
description: measures dissolved inorganic carbon (DIC) A known amount of seawater is dispensed into a stripping chamber where it is acidified and purged with an inert gas. The amount of CO2 in the resulting gas stream is determined by absorbing the CO2 in an absorbent. The pH of the solution is monitored by measuring the transmittance .
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: CTD
type: CTD
description: Conductivity-Temperature-Depth probe
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: flask with closed headspace for discrete CO2 measurement
type: flask with closed headspace for discrete CO2 measurement
description: discrete carbon dioxide (CO2) measurement
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: spectrophotometer
type: spectrophotometer
description: spectrophotometer, optical spectrometer, spectrograph or spectroscope An optical spectrometer (spectrophotometer, spectrograph or spectroscope) is an instrument used to measure properties of light over a specific portion of the electromagnetic spectrum, typically used in spectroscopic analysis to identify materials. Butler, L. R. P.; Laqua, K. (1995). "Nomenclature, symbols, units and their usage in spectrochemical analysis-IX. Instrumentation for the spectral dispersion and isolation of optical radiation (IUPAC Recommendations 1995)". Pure Appl. Chem. IUPAC. 67 (10): 1725–1744. doi:10.1351/pac199567101725. A spectrometer is the general term for describing a combination of spectral apparatus with one or more detectors to measure the intensity of one or more spectral bands."
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: thermosalinograph
type: thermosalinograph
description: automated sea surface temperature and salinity instrument, usually attached to the hull of a ship Thermosalinograph is an automated Sea Surface Temperature and Salinity measurement system making measurement on board a ship using a water intake. [https://www.aoml.noaa.gov/phod/tsg/about.php 2021-01-29]
instrument: (MI_Instrument)
identifier: (MD_Identifier)
code: titrator
type: titrator
description: titrator
platform: (MI_Platform)
identifier: (MD_Identifier)
code: NOAA Ship Ronald H. Brown
description: Updated information from ICES for UNITED STATES platform Ronald H. Brown Flag : UNITED STATES - US (ISO Country Code) Call Sign : WTEC Title : NOAA Ship Platform Class : Research vessel IMO : 9105786 Pennant : R 104 Commissioned Date : 1997-07-19 Current Length : 83.5 Built : 1997 Information Source : http://www.moc.noaa.gov/rb/index.html (URL) Lloyds URL : http://www.seasearcher.com/lmiu/vessels/overview.htm?vesselID=277516 *General Comments:* Name RESEARCHER II planned during build was never used.
instrument: (missing)