# Guaymas Basin 17KYr High Resolution Geochemical Data #----------------------------------------------------------------------- # World Data Center for Paleoclimatology, Boulder # and # NOAA Paleoclimatology Program #----------------------------------------------------------------------- # NOTE: Please cite Publication, and Online_Resource and date accessed when using these data. # If there is no publication information, please cite Investigators, Title, and Online_Resource and date accessed. # # # Online_Resource: https://www.ncdc.noaa.gov/paleo/study/16054 # # Online_Resource: http://www1.ncdc.noaa.gov/pub/data/paleo/contributions_by_author/dean2006b/dean2006b.txt # # Description/Documentation lines begin with # # Data lines have no # # # Archive: Paleoceanography #-------------------- # Contribution_Date # Date: 2014-01-22 #-------------------- # Title # Study_Name: Guaymas Basin 17KYr High Resolution Geochemical Data #-------------------- # Investigators # Investigators: Dean, W.E. #-------------------- # Description_and_Notes # Description: Geochemical data from the Gulf of California, Guaymas Basin cores GGC55 and JPC56. # # Giant gravity core (GGC) 55 and jumbo piston core (JPC) 56 are two of a series of paired, overlapping gravity and piston cores that were collected # in July 1990 on R/V Atlantis II cruise 125/8. These two cores were collected on the western slope of the Guaymas Basin, GGC55 at 27deg28.22'N, # 112deg6.33'W in a water depth of 820m, and JPC56 at 27deg28.16'N, 112deg6.26'W in a water depth of 818m . Both cores were sampled at 10-cm intervals # for geochemical analyses. The samples were analyzed for 40 major, minor, and trace elements by inductively coupled, argon plasma, atomic emission # spectrometry (ICP-AES; Briggs, 2002). Rock standards (USGS) were included with the sediment samples, and 10% of the samples were duplicated. # The precision, determined by analyzing rock standards and duplicate sediment samples, is better than 10%, and usually is better than 5%, at a # concentration of 10 times the limit of detection. Results for 8 major elements (in weight percent) and 19 minor and trace elements # (in parts per million) are given here. # # Dried samples were analyzed for weight percentages of total carbon (TC) and inorganic carbon (IC) by coulometric titration of carbon dioxide following # extraction from the sediment by combustion at 950C and acid volatilization, respectively (Engleman et al., 1985). Percent total organic carbon (% TOC) # was calculated as the difference (TC-IC), and percent CaCO3 was calculated as CaCO3 1/4 IC=0:12; where 0.12 is the fraction of carbon in CaCO3. # The accuracy and precision of this method, determined from hundreds of replicate standards, usually are better than 0.10% for both TC and IC. # # Methods References # # Briggs, P.H., 2002. The determination of forty elements in geological and botanical samples by inductively coupled plasma-atomic emission spectrometry, # In: Taggart, J.E., (Ed.), Analytical methods for chemical analyses of geologic and other materials, U.S. Geological Survey Open-File Report 02-223, pp. G1-20. # # Engleman, E.E., Jackson, L.L., Norton, D.R., Fischer, A.G., 1985. Determination of carbonate carbon in geological materials by coulometric titration. # Chemical Geology 53, 125-128. # # Keigwin, L.D., 2002, Late Pleistocene-Holocene paleoceanography and ventilation of the Gulf of California: Jour. Oceanog., v. 58, p. 421-432. # # #-------------------- # Publication # Authors: Walter E. Dean # Published_Date_or_Year: 2006-09-15 # Published_Title: The geochemical record of the last 17,000 years in the Guaymas Basin, Gulf of California # Journal_Name: Chemical Geology # Volume: 232 # Edition: # Issue: 3-4 # Pages: 87-98 # DOI: 10.1016/j.chemgeo.2006.02.017 # Online_Resource: http://www.sciencedirect.com/science/article/pii/S000925410600129X # Full_Citation: # Abstract: Sediments deposited on the western slope of the Guaymas Basin in the central Gulf of California are composed predominantly of detrital clastic material and biogenic silica (biopal), with minor organic material (average of 2.8% organic carbon) and calcium carbonate. The CaCO3 is derived from calcareous plankton and is highly variable ranging from 0% to 16%. In general, the CaCO3 content of the sediments varies inversely with the biopal content, reflecting the relative abundance of calcareous and siliceous plankton in the photic zone. Siliceous plankton dominate when winds are predominantly out of the northwest producing strong upwelling. Calcareous plankton indicates weak southeasterly winds that bring warm, tropical Pacific surface water into the Gulf. Based mainly on relative abundances of biopal and CaCO3, the sediments deposited over the last 17,000 years in the western Guaymas Basin can be divided into five intervals. In general, the sediments in the intervals with high biopal and low CaCO3 are laminated, but this is not always true. Unlike most other continental margins of the world with well-developed oxygen minimum zones where highest concentrations of organic carbon and redox-sensitive trace metals occur in laminated sediments, the laminated sediments on the anoxic slope of the western Guaymas Basin do not always have the highest concentrations of organic carbon and trace metals such as Mo and Cd. #------------------ # Publication # Authors: John A. Barron, David Bukry, Walter E. Dean # Published_Date_or_Year: 2005-08-01 # Published_Title: Paleoceanographic history of the Guaymas Basin, Gulf of California, during the past 15,000 years based on diatoms, silicoflagellates, and biogenic sediments # Journal_Name: Marine Micropaleontology # Volume: 56 # Edition: # Issue: 3-4 # Pages: 81-102 # DOI: 10.1016/j.marmicro.2005.04.001 # Online_Resource: http://www.sciencedirect.com/science/article/pii/S0377839805000356 # Full_Citation: # Abstract: High-resolution records of calcium carbonate, biogenic opal, diatoms, and silicoflagellates from western Guaymas Basin gravity core GGC55 and piston core JPC56 and eastern Guaymas Basin DSDP Site 480 reveal a complex paleoceanographic history of the central Gulf of California during the past 15,000 years. Prior to ~6.2 ka, the eastern and western Guaymas Basin proxy records were remarkably similar. After conditions similar to those of today during the Bolling-Allerod, the Younger Dryas (YD) saw a major drop in diatom production, coincident with increased calcium carbonate and tropical microfossils suggestive of El Nino-like conditions. Biosiliceous productivity began increasing during the latter part of the YD, but it was only during the earliest Holocene (11.6 to 11.0 ka) that conditions similar to those of the Bolling-Allerod returned to the central Gulf. Between around 11.0 and 6.2 ka, tropical diatoms and silicoflagellates were virtually absent from the central Gulf, as relatively cooler and fresher surface waters resembling those of the modern northern Gulf were present in the central Gulf. Beginning at about 6.2 ka, tropical diatoms and silicoflagellates began increasing in the central Gulf, and coccoliths returned to western Gulf sediments. The onset of modern-day monsoon conditions in the American Southwest required the presence of warm SSTs in the northern Gulf, which probably did not occur until after about 5.4 ka, when tropical diatoms and silicoflagellates became relatively common in the central Gulf. Modern east-west contrasts, which arise from late winter-early spring coastal upwelling on the mainland side and lower diatom productivity on the western side of the Gulf, commenced between 6.2 and 5.4 ka, possibly due to a shift in the direction of late winter-early spring winds more towards the southeast, or down the axis of the Gulf. This proposed wind shift might have ultimately been due to a late Holocene strengthening of ENSO-like conditions in the eastern equatorial Pacific. #------------------ # Publication # Authors: Lloyd D. Keigwin # Published_Date_or_Year: 2002-04-01 # Published_Title: Late Pleistocene-Holocene Paleoceanography and Ventilation of the Gulf of California # Journal_Name: Journal of Oceanography # Volume: 58 # Edition: # Issue: 2 # Pages: 421-432 # DOI: 10.1023/A:1015830313175 # Online_Resource: http://link.springer.com/article/10.1023/A%3A1015830313175 # Full_Citation: # Abstract: Sediment cores collected in 1990 from the Gulf of California have been studied using stable isotope and radiocarbon techniques to reconstruct the climate and ventilation histories since the last glacial maximum. Benthic foraminiferal d18O from core tops in a water depth range of 145 to 1442 m increases by about 2% with increasing depth. This is consistent with a composite temperature profile constructed from several hydrocasts in the various gulf basins. However, the d18O water/salinity relationship is not sufficiently linear in gulf locations or in nearby open Pacific Geochemical Ocean Sections Study (GEOSECS) stations to be useful in solving paleotemperature equations. Of the most common benthic foraminifera, only Planulina ariminensis has d13C that is consistent with the measured d13C of ECO2. Several cores in the depth range 500 to 900 m have the laminated Holocene and Bolling/Allerod sediments, and the nonlaminated glacial age and Younger Dryas sediments that are typical of the gulf and other locations such as Santa Barbara Basin. The best of those, Jumbo Piston Core (JPC) 56 from 818 m water depth on the western margin of Guaymas Basin, was sampled for intensive study. Oxygen isotope ratios in benthic and planktonic foraminifera show little evidence for deglacial temperature oscillations. Carbon isotope ratios are generally lower during warm epochs, but the most striking result is strongly lowered benthic and planktonic d13C about 9500 years ago. This may reflect water column oxidation of locally released methane. Neither benthic d13C in depth section nor paired benthic and planktonic 14C data in JPC56 are consistent with increased intermediate water ventilation during the glacial maximum and Younger Dryas. Likewise, 14C data from 5 pairs of foraminifera from the Okhotsk Sea fail to support better ventilation in that basin during the last glacial maximum. #------------------ # Publication # Authors: Carol Pride, Robert Thunell, Daniel Sigman, Lloyd Keigwin, Mark Altabet, Eric Tappa # Published_Date_or_Year: 1999-06-01 # Published_Title: Nitrogen isotopic variations in the Gulf of California since the Last Deglaciation: Response to global climate change # Journal_Name: Paleoceanography # Volume: 14 # Edition: # Issue: 3 # Pages: 397-409 # DOI: 10.1029/1999PA900004 # Online_Resource: http://onlinelibrary.wiley.com/doi/10.1029/1999PA900004/abstract # Full_Citation: # Abstract: High-resolution records of the nitrogen isotopic composition of organic matter (d15Norg), opal content, and opal accumulation rates from the central Gulf of California reveal large and abrupt variations during deglaciation and gradual Holocene changes coincident with climatic changes recorded in the North Atlantic. Homogenous sediments with relatively low d15Norg values and low opal content were deposited at the end of the last glacial period, during the Younger-Dryas event, and during the middle to late Holocene. In contrast, laminated sediments deposited in the two deglacial stages are characterized by very high d15Norg values (>14 per mil) and opal accumulation rates (29-41 mg cm-2 yr-1). Abrupt shifts in d15Norg were driven by widespread changes in the extent of suboxic subsurface waters supporting denitrification and were amplified in the central gulf record due to variations in upwelling, vertical mixing, and/or the latitudinal position of the Intertropical Convergence Zone. #------------------ # Funding_Agency # Funding_Agency_Name: US Geological Survey # Grant: #------------------ # Site_Information # Site_Name: GGC-55 # Location: Ocean>Pacific Ocean>Eastern Pacific Ocean # Country: # Northernmost_Latitude: 27.4703 # Southernmost_Latitude: 27.4703 # Easternmost_Longitude: -112.0877 # Westernmost_Longitude: -112.0877 # Elevation: -820 m #------------------ # Data_Collection # Collection_Name: GGC55Geochem2006 # Earliest_Year: 17300 # Most_Recent_Year: 2230 # Time_Unit: Cal Year BP # Core_Length: m # Notes: #------------------ # Chronology: # # # #---------------- # Variables # # Data variables follow (have no #) # Data line variables format: Variables list, one per line, shortname-tab-longname-tab-longname components (9 components: what, material, error, units, seasonality, archive, detail, method, C or N for Character or Numeric data) ## depth_cmJPC56 depth, , , cm, , , JPC56, ,N ## depth_cmGGC55 depth, , , cm, , , GGC55 - depth of sample in core GGC55 to 220 cm - then depth of sample from JPC56 relative to correlative depth in GGC55, ,N ## age_calkaBP age, , , calendar kyears before present, , , , ,N ## Al%-s Aluminum, , , %, , , , ICP,N ## Fe%-s Iron, , , %, , , , ICP,N ## Mg%-s Magnesium, , , %, , , , ICP,N ## Ca%-s Calcium, , , %, , , , ICP,N ## Na%-s Sodium, , , %, , , , ICP,N ## K%-s Potassium, , , %, , , , ICP,N ## P%-s Phosphorus, , , %, , , , ICP,N ## Ti%-s Titanium, , , %, , , , ICP,N ## Mn ppm Manganese, , , %, , , , ICP,N ## Be ppm Beryllium, , , %, , , , ICP,N ## Cr ppm Chromium, , , %, , , , ICP,N ## Co ppm Cobalt, , , %, , , , ICP,N ## Ni ppm Nickel, , , %, , , , ICP,N ## Cu ppm Copper, , , %, , , , ICP,N ## V ppm Vanadium, , , %, , , , ICP,N ## Zn ppm Zinc, , , %, , , , ICP,N ## As ppm Arsenic, , , %, , , , ICP,N ## Sc ppm Scandium, , , %, , , , ICP,N ## Sr ppm Strontium, , , %, , , , ICP,N ## Ba ppm Barium, , , %, , , , ICP,N ## Y ppm Yttrium, , , %, , , , ICP,N ## Zr ppm Zirconium, , , %, , , , ICP,N ## Mo ppm Molybdenum, , , %, , , , ICP,N ## Cd ppm Cadmium, , , %, , , , ICP,N ## La ppm Lanthanum, , , %, , , , ICP,N ## Pb ppm Lead, , , %, , , , ICP,N ## Li ppm Lithium, , , %, , , , ICP,N ## carb%-s Calcium Carbonate, inorganic carbon, , %, , , , ICP,N ## toc% Total Organic Carbon, , , %, , , , ICP,N #---------------- # Data: # Data lines follow (have no #) # Data line format - tab-delimited text, variable short name as header # Missing Values: depth_cmJPC56 depth_cmGGC55 age_calkaBP Al%-s Fe%-s Mg%-s Ca%-s Na%-s K%-s P%-s Ti%-s Mn ppm Be ppm Cr ppm Co ppm Ni ppm Cu ppm V ppm Zn ppm As ppm Sc ppm Sr ppm Ba ppm Y ppm Zr ppm Mo ppm Cd ppm La ppm Pb ppm Li ppm carb%-s toc% 9 2.23 5.36 2.17 1.49 5.42 3.93 1.65 0.10 0.22 207 1.1 52 9 56 39 79 110 17 8.2 382 465 14 69 15 5 18 14 36 10.25 4.34 20 2.34 5.27 2.25 1.45 4.16 3.51 1.61 0.10 0.22 200 1.1 52 8 51 40 75 108 18 8.1 320 477 14 66 15 4 18 13 35 7.58 4.02 30 2.45 5.68 2.41 1.50 4.38 3.59 1.74 0.11 0.24 218 1.1 57 9 53 40 88 114 20 8.6 337 491 15 74 15 5 19 14 37 7.42 4.40 40 2.56 5.73 2.43 1.51 4.90 3.60 1.71 0.11 0.23 216 1.1 50 10 55 38 92 114 28 8.7 359 497 15 73 16 5 20 14 37 8.67 4.37 50 2.67 4.62 1.89 1.45 4.35 3.92 1.42 0.10 0.19 211 0.9 45 6 43 33 83 92 15 7.1 321 421 12 60 17 4 16 12 30 6.67 3.45 59 2.77 4.53 1.96 1.32 5.35 3.69 1.37 0.08 0.19 190 0.9 47 7 41 38 79 96 19 7.0 357 431 12 62 18 2 16 11 29 9.42 3.07 70 2.89 3.73 1.50 1.34 4.52 4.71 1.24 0.07 0.15 166 0.8 40 5 36 26 85 75 12 5.7 309 406 10 49 20 3 13 11 26 8.33 3.38 80 2.99 5.50 2.35 1.61 2.10 3.96 1.65 0.09 0.23 232 1.1 50 8 47 40 102 111 16 8.6 229 496 14 73 16 3 18 15 37 2.33 4.18 90 3.10 4.93 1.96 1.50 1.94 4.28 1.52 0.10 0.20 210 1.0 45 7 44 35 95 98 14 7.5 213 467 13 64 18 3 17 13 33 1.83 3.83 100 3.21 4.93 2.05 1.52 3.68 3.95 1.50 0.09 0.20 218 1.0 46 7 42 33 91 95 15 7.6 286 444 13 64 17 3 17 12 33 6.25 3.35 110 3.32 4.32 1.74 1.36 5.09 4.19 1.35 0.10 0.17 197 0.8 43 6 40 32 85 85 12 6.5 347 428 11 53 18 3 14 11 28 8.42 3.40 120 3.43 3.50 1.40 1.29 3.26 4.84 1.14 0.09 0.15 141 0.7 35 5 31 24 85 68 11 5.4 245 330 9 46 19 2 12 9 23 5.92 2.54 130 3.53 4.20 1.71 1.27 5.31 3.46 1.31 0.07 0.17 179 0.8 40 6 35 28 84 79 11 6.5 356 395 10 53 13 2 14 11 29 11.00 2.91 140 3.64 5.78 2.27 1.52 7.29 3.37 1.76 0.10 0.23 261 1.1 54 9 51 40 97 109 16 8.6 472 528 14 74 14 4 19 15 40 14.50 4.13 150 3.75 5.60 2.19 1.49 7.00 3.43 1.69 0.10 0.23 228 1.2 53 9 49 39 105 110 19 8.7 461 495 15 72 16 5 19 15 38 13.67 4.00 160 3.86 4.72 1.86 1.30 5.79 3.41 1.42 0.08 0.19 210 0.9 43 7 41 31 81 92 15 7.0 386 409 12 59 15 3 15 12 30 12.17 3.18 170 3.97 4.17 1.79 1.31 6.23 3.94 1.33 0.34 0.17 184 0.8 42 6 39 30 76 91 10 6.3 422 455 11 52 16 3 14 11 28 11.33 3.58 180 4.08 4.43 1.80 1.33 5.94 3.81 1.39 0.08 0.19 194 0.9 42 6 38 32 87 88 10 6.8 400 687 11 58 16 2 15 11 30 11.50 3.03 190 4.18 4.40 1.71 1.36 7.02 4.00 1.39 0.09 0.18 185 0.9 44 6 42 31 89 86 9 6.7 477 1240 11 57 16 3 15 12 29 14.42 3.34 200 4.29 5.50 2.07 1.50 7.01 3.48 1.69 0.10 0.23 227 1.1 56 8 49 40 111 107 14 8.3 478 731 14 74 14 3 19 14 38 14.42 3.93 209 4.39 6.32 2.46 1.63 7.83 3.32 1.90 0.11 0.26 252 1.2 61 9 54 43 139 122 21 9.7 521 829 16 81 14 5 21 16 43 15.08 4.00 220 4.51 4.80 1.91 1.38 4.28 3.82 1.45 0.08 0.19 181 0.9 45 7 42 35 102 99 15 7.2 311 444 12 62 16 2 15 13 31 10.17 2.96 9 229 4.61 4.68 2.09 1.52 4.34 4.21 1.47 0.1 0.21 196 1.4 48 7 42 45 81 722 12 6.9 316 459 12.3 68.5 14 1 14.9 13 35 7.75 4.12 20 240 4.72 4.85 2.25 1.40 4.23 3.89 1.45 0.09 0.20 204 1.0 52 8 44 41 99 374 21 7.5 314 432 13 63 13 4 16 13 31 8.42 4.40 30 250 4.83 5.21 2.16 1.50 4.62 4.06 1.56 0.10 0.21 201 1.0 50 9 48 38 81 124 19 8.0 340 469 14 66 14 2 17 13 33 8.42 4.27 39 259 4.93 5.59 2.51 1.65 4.49 3.7 1.67 0.11 0.25 219 1.6 55 9 51 38 96 162 21 8.3 330 460 16.1 82.4 15 2 18.5 11 41 8.17 4.60 49 269 5.04 4.71 1.97 1.46 3.39 4.49 1.47 0.09 0.20 198 1.0 45 7 42 33 92 118 16 7.1 271 421 12 62 18 3 16 12 31 5.33 3.68 59 279 5.15 4.33 1.91 1.27 5.58 3.77 1.32 0.07 0.17 193 0.8 41 6 37 31 93 89 12 6.5 365 409 11 55 20 2 14 11 29 11.17 3.02 69 289 5.25 4.81 2.09 1.51 4.07 3.94 1.48 0.09 0.21 198 1.4 48 7 40 34 86 104 12 7.1 295 443 12.9 68.7 15 2 15.9 10 36 7.42 3.64 79 299 5.36 4.94 2.20 1.43 6.52 3.66 1.48 0.09 0.20 208 1.0 46 7 44 37 105 97 16 7.4 424 463 12 63 16 2 16 14 33 12.50 3.61 89 309 5.47 4.19 1.59 1.40 5.27 4.09 1.30 0.08 0.17 168 0.8 40 5 35 30 94 80 9 6.3 338 249 11 54 10 2 14 11 29 12.92 2.91 109 329 5.69 3.47 1.44 1.48 1.3 4.29 1.09 0.08 0.15 133 1.1 38 5 31 30 81 75 5 5.2 149 220 8.9 52.7 8 1 11.6 8 26 1.92 2.91 119 339 5.80 4.49 1.70 1.45 4.59 4.62 1.37 0.08 0.18 172 0.9 40 6 33 29 99 82 11 6.6 317 298 11 57 8 1 14 12 29 8.67 2.91 129 349 5.90 4.81 1.82 1.61 1.77 4.51 1.46 0.08 0.19 171 1.0 44 6 37 32 108 95 13 7.3 199 393 12 62 8 2 16 14 31 4.33 2.66 139 359 6.01 3.25 1.34 1.28 0.94 4.02 1.07 0.06 0.14 118 1 35 4 28 26 82 71 4 4.9 128 255 8.6 50.5 8 2 10.9 8 26 0.00 2.75 147 367 6.10 4.21 1.58 1.41 3.88 4.14 1.26 0.08 0.16 156 0.8 40 5 34 26 95 80 12 6.2 283 370 10 55 8 2 14 12 27 7.33 2.64 159 379 6.23 4.58 1.69 1.38 2.79 4.09 1.36 0.07 0.18 195 0.9 41 6 35 30 106 90 13 6.9 229 394 12 60 9 1 16 13 30 4.17 2.71 169 389 6.34 4.99 1.99 1.51 4.29 3.57 1.54 0.08 0.21 201 1.5 42 6 34 31 93 87 7 7.4 292 429 11.9 73.6 6 1 15.7 10 39 8.67 2.91 179 399 6.44 4.47 1.59 1.46 1.00 4.49 1.38 0.07 0.18 158 1.0 41 5 36 29 103 82 10 6.9 156 365 11 58 8 2 15 14 29 0.25 3.19 189 409 6.55 5.38 1.95 1.62 1.78 4.50 1.66 0.09 0.21 192 1.1 48 7 40 34 110 99 13 8.0 198 465 13 66 8 2 18 15 36 2.42 3.33 197 417 6.64 3.87 1.52 1.37 1.52 3.7 1.21 0.08 0.16 153 1.2 37 5 29 25 83 77 5 5.7 161 292 10.1 55.1 7 2 12.9 9 28 2.25 2.81 209 429 6.77 4.65 1.67 1.48 1.77 4.39 1.37 0.07 0.18 167 0.9 37 6 33 28 93 83 10 6.7 188 378 10 64 8 1 14 13 29 2.42 2.56 219 439 6.88 5.13 1.77 1.57 1.18 4.41 1.55 0.18 0.20 174 1.1 48 6 40 32 114 99 10 8.0 183 408 14 67 9 2 18 16 34 0.42 3.45 229 449 6.99 4.02 1.62 1.42 1.54 3.92 1.21 0.07 0.18 166 1.3 42 5 31 27 86 86 5 6.1 164 384 10.6 59.7 8 2 14.3 9 30 2.00 2.68 239 459 7.09 4.73 1.66 1.58 1.03 5.14 1.46 0.08 0.19 168 1.1 42 6 35 31 99 84 13 7.2 153 325 12 61 10 2 17 14 30 0.00 2.72 259 479 7.30 4.99 1.77 1.41 1.06 3.36 1.48 0.08 0.20 190 1.1 46 6 38 36 109 91 10 7.5 160 424 12 63 8 2 17 14 32 0.33 3.06 269 489 7.39 5.04 1.91 1.58 2 3.84 1.54 0.08 0.21 212 1.5 47 6 36 32 99 95 7 7.5 191 433 13.8 70.5 7 2 16.9 11 38 2.00 3.17 279 499 7.48 4.45 1.54 1.37 1.14 4.26 1.38 0.06 0.17 158 1.0 39 5 34 29 90 77 8 6.8 152 506 12 58 8 2 15 12 29 0.75 2.97 289 509 7.58 4.54 1.57 1.41 0.90 4.45 1.42 0.09 0.18 154 1.0 41 6 34 30 90 81 10 6.9 147 393 12 62 9 2 16 13 30 0.00 2.90 298 518 7.66 4.25 1.65 1.45 1.48 3.98 1.34 0.08 0.18 180 1.3 43 5 32 27 84 84 6 6.5 164 374 11.8 58.6 7 2 14.1 9 32 1.42 2.92 309 529 7.76 4.74 1.73 1.43 0.89 4.17 1.48 0.08 0.19 169 1.1 44 6 36 30 97 86 9 7.4 148 403 13 64 8 2 17 14 31 0.00 4.01 319 539 7.85 4.78 1.67 1.50 0.86 4.55 1.51 0.07 0.19 164 1.0 45 6 36 33 102 87 10 7.3 144 418 11 63 9 2 16 14 32 0.00 4.91 329 549 7.94 4.28 1.77 1.52 3.52 4.08 1.32 0.08 0.19 206 1.4 43 5 33 30 82 80 5 7.2 229 342 13.9 63.9 8 1 15.4 8 31 6.92 2.70 339 559 8.03 4.50 1.64 1.42 1.44 4.54 1.41 0.07 0.17 164 0.9 39 5 35 29 98 82 9 6.3 165 354 9 55 8 2 14 13 29 1.58 2.49 349 569 8.12 5.04 1.77 1.52 1.52 4.12 1.52 0.08 0.19 180 1.0 46 6 37 30 104 90 11 7.6 174 368 13 64 8 2 17 14 32 1.33 3.17 359 579 8.21 5 1.98 1.57 1.12 3.71 1.48 0.08 0.22 197 1.6 45 7 36 35 101 98 6 7.6 166 438 12 74.2 9 2 16.4 10 36 0.25 2.98 369 589 8.30 4.84 1.91 1.63 1.25 4.96 1.68 0.07 0.19 172 1.0 40 6 34 31 101 87 11 7.0 176 342 11 59 8 2 17 13 30 0.58 2.76 379 599 8.39 4.78 1.91 1.63 1.16 4.74 1.65 0.06 0.19 177 1.0 38 6 34 31 98 91 9 7.1 169 433 10 60 9 2 17 14 30 0.50 2.56 389 609 8.48 3.96 1.53 1.3 1.2 3.71 1.24 0.06 0.17 153 1.2 34 5 27 25 75 77 6 5.8 141 274 9.8 57.7 7 1 12.9 9 28 1.08 2.53 399 619 8.57 4.84 1.85 1.61 0.97 4.59 1.66 0.07 0.19 163 1.1 43 6 36 32 106 86 10 7.1 164 385 11 61 8 3 18 14 31 0.00 2.96 409 629 8.66 4.67 1.84 1.42 3.13 3.76 1.57 0.07 0.18 183 1.0 37 5 34 31 93 76 9 7.0 238 410 12 58 7 2 17 13 29 3.92 2.60 421 641 8.76 3.95 1.56 1.42 3.98 4.04 1.25 0.08 0.17 182 1.3 41 5 31 31 77 76 6 6.3 249 484 12.9 58.7 10 2 14.5 8 30 6.50 2.57 429 649 8.83 5.25 1.96 1.56 1.70 4.22 1.73 0.07 0.19 184 1.1 39 6 34 30 105 90 10 7.7 191 472 13 65 8 1 20 13 32 1.83 2.55 439 659 8.92 4.99 1.96 1.65 1.17 4.70 1.67 0.08 0.20 182 1.1 48 6 40 34 111 94 10 7.5 175 440 12 69 10 2 20 13 30 0.17 2.91 449 669 9.00 5.29 2.01 1.6 1.08 3.74 1.65 0.08 0.22 198 1.6 49 6 37 35 97 94 7 7.6 169 449 12.3 74.6 8 3 17.2 12 39 0.33 3.07 459 679 9.09 4.82 1.86 1.61 1.16 4.54 1.63 0.09 0.18 170 1.1 41 6 37 33 101 95 11 7.2 168 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449 15 57 5 3 19 16 31 6.00 2.40 1449 1669 15.60 4.22 1.75 1.30 3.32 2.87 1.38 0.07 0.17 187 1.0 41 5 31 28 72 74 5 6.3 246 373 12 50 5 3 17 15 28 7.17 2.36 1460 1680 15.66 4.95 1.92 1.31 5.04 2.45 1.55 0.08 0.20 216 1.1 42 5 35 33 78 81 8 7.3 340 457 14 58 4 4 20 18 33 11.25 2.46 1470 1690 15.70 5.00 2.00 1.41 3.87 2.88 1.58 0.08 0.20 213 1.1 43 5 30 30 79 83 7 7.2 287 455 13 59 5 3 20 17 33 7.92 2.12 1480 1700 15.75 5.05 2.06 1.39 4.47 2.58 1.60 0.08 0.20 220 1.1 48 5 31 30 85 85 10 7.5 307 432 14 59 6 1 20 17 33 8.58 2.15 1490 1710 15.79 4.68 1.96 1.39 6.08 2.93 1.49 0.09 0.18 218 1.1 45 5 29 30 77 85 8 7.0 406 420 14 54 6 2 19 18 31 12.50 2.31 1499 1719 15.83 4.23 1.93 1.33 2.99 3.02 1.35 0.16 0.17 191 1.0 44 5 31 31 79 83 8 6.4 258 378 12 50 9 6 17 16 27 6.75 3.20 1510 1730 15.88 5.10 1.98 1.30 2.45 2.54 1.60 0.11 0.21 189 1.1 48 6 37 33 91 88 9 7.2 211 439 14 60 7 4 19 19 32 4.33 3.86 1521 1741 15.93 5.10 2.09 1.43 4.94 2.61 1.58 0.09 0.20 216 1.1 50 6 33 31 93 83 7 7.7 323 446 14 60 5 3 20 17 34 11.17 2.66 1531 1751 15.97 5.42 2.18 1.39 5.74 2.37 1.69 0.09 0.22 235 1.2 51 6 34 32 90 86 9 7.9 379 499 15 64 5 4 22 18 35 12.58 2.34 1540 1760 16.01 5.79 2.37 1.46 5.26 2.36 1.78 0.10 0.23 242 1.3 53 7 37 36 94 97 12 8.6 365 521 16 68 7 4 23 20 37 10.08 2.87 1549 1769 16.04 5.91 2.49 1.42 5.12 2.13 1.81 0.10 0.25 261 1.3 52 7 33 34 91 98 14 8.7 374 527 17 70 8 4 24 18 37 7.92 2.93 1560 1780 16.09 5.75 2.57 1.41 4.05 2.26 1.78 0.10 0.23 247 1.3 47 6 32 31 88 92 12 8.4 324 528 17 67 10 4 24 18 37 8.67 2.53 1570 1790 16.13 5.87 2.41 1.47 5.26 2.30 1.82 0.10 0.24 257 1.3 52 7 34 33 90 94 12 8.7 373 506 17 67 9 3 24 20 38 9.92 2.74 1580 1800 16.17 5.47 2.24 1.38 5.09 2.35 1.72 0.12 0.22 237 1.2 49 6 33 30 82 87 12 8.4 363 519 16 63 8 3 22 18 36 9.67 2.62 1590 1810 16.21 5.34 2.21 1.32 5.91 2.06 1.64 0.09 0.21 234 1.2 48 6 30 29 75 84 8 7.9 393 491 15 60 7 2 21 17 34 11.75 2.67 1599 1819 16.25 6.24 2.59 1.45 5.01 2.16 1.93 0.10 0.25 276 1.4 56 7 34 34 88 96 12 9.0 372 533 17 69 9 1 25 18 39 10.92 2.51 1610 1830 16.29 5.64 2.49 1.39 5.15 2.21 1.75 0.09 0.23 248 1.3 48 7 30 31 81 90 13 8.4 367 521 16 66 8 3 23 17 36 9.25 2.53 1620 1840 16.33 5.14 2.32 1.25 5.86 2.03 1.58 0.09 0.21 228 1.1 45 6 28 29 76 82 12 7.5 362 452 14 60 9 2 21 15 32 8.42 2.51 1630 1850 16.37 6.11 2.51 1.40 4.18 2.04 1.89 0.09 0.25 271 1.3 56 7 33 34 86 95 12 9.0 310 494 17 70 8 2 25 19 39 7.92 2.69 1640 1860 16.41 5.82 2.46 1.36 4.54 2.24 1.81 0.09 0.24 247 1.3 52 6 31 31 79 90 9 8.5 311 473 17 67 9 2 23 17 36 7.17 2.46 1649 1869 16.45 5.86 2.40 1.39 4.96 2.03 1.82 0.09 0.24 343 1.3 52 7 32 31 79 92 11 8.7 348 490 17 67 7 2 24 18 38 10.83 2.41 1660 1880 16.49 6.19 2.50 1.46 3.63 2.15 1.90 0.10 0.25 246 1.4 48 7 33 32 83 95 12 9.3 283 507 18 75 9 1 26 19 40 6.00 2.53 1670 1890 16.52 6.11 2.56 1.43 4.12 2.12 1.90 0.09 0.25 256 1.4 52 7 33 34 84 96 11 9.0 298 492 17 72 8 1 25 19 40 7.42 2.52 1680 1900 16.56 6.14 2.59 1.45 5.17 1.96 1.89 0.09 0.24 257 1.4 54 7 34 34 86 95 10 9.1 363 502 17 70 10 2 25 19 40 11.00 2.56 1690 1910 16.60 5.87 2.50 1.47 4.21 2.27 1.83 0.09 0.23 254 1.3 47 7 32 33 83 95 13 8.9 322 486 17 68 14 1 24 19 40 9.08 2.40 1699 1919 16.63 6.25 2.64 1.47 3.08 2.25 1.96 0.09 0.25 267 1.4 52 7 34 35 88 100 12 9.1 266 492 17 71 16 2 25 20 40 4.92 2.51 1710 1930 16.67 5.79 2.25 1.31 5.95 1.89 1.80 0.09 0.23 253 1.2 43 6 30 30 78 85 11 8.4 373 508 16 67 11 2 24 18 36 10.00 2.00 1720 1940 16.70 6.62 2.83 1.49 5.08 2.20 2.06 0.10 0.27 287 1.4 51 8 36 35 92 98 16 9.4 378 542 18 75 15 3 27 21 41 10.00 2.22 1730 1950 16.74 6.20 2.56 1.42 4.34 2.05 1.93 0.09 0.26 270 1.3 45 7 36 34 90 92 13 9.0 334 505 17 71 12 2 25 18 39 8.75 2.58 1740 1960 16.77 6.55 2.62 1.48 3.42 2.09 2.02 0.10 0.27 273 1.3 46 8 38 36 94 99 12 9.3 291 518 18 75 14 2 27 20 41 6.08 2.16 1749 1969 16.81 6.07 2.58 1.38 4.94 2.05 1.86 0.09 0.25 266 1.3 50 7 33 32 84 90 10 8.9 343 497 18 71 19 2 24 17 38 6.17 2.00 1760 1980 16.84 5.78 2.63 1.42 2.97 2.36 1.83 0.09 0.24 272 1.2 50 7 33 32 86 93 9 8.5 260 494 16 66 21 3 24 16 37 4.83 2.15 1770 1990 16.88 5.70 2.35 1.42 4.30 2.30 1.78 0.09 0.24 285 1.3 46 7 32 32 83 88 9 8.7 330 489 17 67 13 4 24 17 37 9.25 2.24 1780 2000 16.91 5.85 2.39 1.43 4.15 2.26 1.83 0.08 0.24 274 1.3 42 7 35 36 83 88 9 8.7 323 470 17 70 8 2 25 18 38 9.25 1.95 1790 2010 16.94 6.07 2.52 1.41 4.59 2.11 1.92 0.09 0.25 268 1.3 51 7 34 34 88 92 8 8.9 332 496 17 72 6 3 24 18 39 7.83 2.20 1799 2019 16.97 6.52 2.81 1.48 3.53 2.36 2.02 0.10 0.27 280 1.4 54 7 37 37 93 100 13 9.6 293 492 18 74 9 2 26 20 42 6.50 3.15 1810 2030 17.01 5.60 2.37 1.43 1.92 2.59 1.77 0.08 0.24 240 1.2 48 6 36 35 83 91 9 8.2 209 433 16 68 14 2 23 16 36 1.92 2.17 1820 2040 17.04 5.54 2.24 1.42 5.41 2.36 1.72 0.09 0.22 264 1.3 49 7 34 36 86 89 8 8.5 375 460 16 65 10 3 23 17 37 11.58 2.43 1830 2050 17.07 6.16 2.39 1.47 5.96 2.13 1.94 0.09 0.24 260 1.3 47 7 35 35 95 94 11 9.1 410 509 17 71 9 3 25 20 41 12.75 2.29 1840 2060 17.10 6.00 2.61 1.47 3.21 2.39 1.91 0.10 0.25 245 1.3 50 7 39 38 95 99 17 8.8 285 472 16 71 13 2 24 20 40 5.67 2.50 1849 2069 17.13 6.19 2.49 1.41 5.70 2.21 1.95 0.10 0.25 271 1.3 52 8 35 35 90 95 14 9.0 396 517 17 69 10 2 24 19 40 10.42 2.13 1860 2080 17.16 6.36 2.81 1.49 5.06 2.35 1.96 0.10 0.27 276 1.3 52 8 41 39 94 99 17 9.3 375 510 17 73 14 2 26 19 40 9.25 2.20 1870 2090 17.19 5.61 2.41 1.34 6.09 2.18 1.79 0.09 0.22 252 1.3 48 6 33 33 85 87 12 8.4 386 457 16 65 14 2 23 18 37 8.92 2.27 1880 2100 17.22 5.90 2.33 1.40 4.83 2.32 1.86 0.09 0.24 265 1.2 48 7 35 36 87 92 10 8.6 334 470 16 67 13 2 24 19 38 9.17 2.40 1890 2110 17.24 5.55 2.32 1.39 4.88 2.43 1.75 0.09 0.23 269 1.2 48 6 34 33 84 87 7 8.5 349 466 16 64 12 2 23 16 37 10.08 2.33 1899 2119 17.27 5.32 2.30 1.27 2.30 2.72 1.72 0.09 0.22 191 1.1 48 6 35 37 83 90 7 7.7 210 409 14 62 21 2 22 17 35 0.00 2.24 1910 2130 17.30 5.15 2.29 1.47 1.07 3.11 1.68 0.08 0.22 224 1.2 51 6 33 35 78 93 7 7.6 174 405 14 65 15 3 22 18 35 0.00 2.52